CAS 944451-26-7

Dichloro[(1,2,3,4,5,6-η)-1-methyl-4-(1-methylethyl)benzene][1,1′-[(1R)-5,5′,6,6′,7,7′,8,8′-octahydro[1,1′-binaphthalene]-2,2′-diyl]bis[1,1-diphenylphosphine-κP]]ruthenium

Description:

Dichloro[(1,2,3,4,5,6-η)-1-methyl-4-(1-methylethyl)benzene][1,1′-[(1R)-5,5′,6,6′,7,7′,8,8′-octahydro[1,1′-binaphthalene]-2,2′-diyl]bis[1,1-diphenylphosphine-κP]]ruthenium, with CAS number 944451-26-7, is a complex organometallic compound featuring a ruthenium center coordinated to various ligands. This compound exhibits characteristics typical of transition metal complexes, including potential catalytic activity in various chemical reactions, particularly in organic synthesis and asymmetric catalysis. The presence of phosphine ligands enhances its stability and reactivity, while the unique structure of the binaphthalene derivative contributes to its chiral properties, making it useful in enantioselective transformations. The dichloro substituents indicate that it can participate in further reactions, potentially allowing for the substitution of chlorine atoms with other ligands or substrates. Overall, this compound is of interest in the field of coordination chemistry and catalysis, showcasing the versatility of ruthenium complexes in synthetic applications.

Formula: C₅₄H₅₄Cl₂P₂Ru

InChI: InChI=1S/C44H40P2.C10H14.2ClH.Ru/c1-5-19-35(20-6-1)45(36-21-7-2-8-22-36)41-31-29-33-17-13-15-27-39(33)43(41)44-40-28-16-14-18-34(40)30-32-42(44)46(37-23-9-3-10-24-37)38-25-11-4-12-26-38;1-8(2)10-6-4-9(3)5-7-10;;;/h1-12,19-26,29-32H,13-18,27-28H2;4-8H,1-3H3;2*1H;/q;;;;+2/p-2

InChI key: InChIKey=RDVYAXZMACLMGN-UHFFFAOYSA-L

SMILES: [Cl-][Ru+2]123456([Cl-])(C=7(C(C)C)[CH]1=[CH]2C3(C)=[CH]4[CH]57)[P](C=8C(C=9C([P]6(C%10=CC=CC=C%10)C%11=CC=CC=C%11)=CC=C%12C9CCCC%12)=C%13C(=CC8)CCCC%13)(C%14=CC=CC=C%14)C%15=CC=CC=C%15

Synonyms:

• Dichloro[(1,2,3,4,5,6-η)-1-methyl-4-(1-methylethyl)benzene][1,1′-[(1R)-5,5′,6,6′,7,7′,8,8′-octahydro[1,1′-binaphthalene]-2,2′-diyl]bis[1,1-diphenylphosphine-κP]]ruthenium
• Ruthenium, dichloro[(1,2,3,4,5,6-η)-1-methyl-4-(1-methylethyl)benzene][1,1′-[(1R)-5,5′,6,6′,7,7′,8,8′-octahydro[1,1′-binaphthalene]-2,2′-diyl]bis[1,1-diphenylphosphine-κP]]-

Chloro[(R)-(+)-2,2'-bis(diphenylphosphino)-5,5',6,6',7,7',8,8'-octahydro-1,1'-binaphthyl](p-cymene)ruthenium(II) chloride [RuCl(p-cymene)((R)-H₈-binap)]Cl

CAS: 944451-26-7

Chloro[(R)-(+)-2,2'-bis(diphenylphosphino)-5,5',6,6',7,7',8,8'-octahydro-1,1'-binaphthyl](p-cymene)ruthenium(II) chloride [RuCl(p-cymene)((R)-H8-binap)]Cl

Formula: C₅₄H₅₄ClP₂RuCl

Color and Shape: pale yellow pwdr.

Molecular weight: 936.93

Ref: 08-44-0094

Chloro[(R)-(+)-2,2'-bis(diphenylphosphino)-5,5',6,6',7,7',8,8'-octahydro-1,1'-binaphthyl](p-cymene)ruthenium(II) chloride

CAS: 944451-26-7

Formula: C₅₄H₅₄Cl₂P₂Ru

Color and Shape: Solid

Molecular weight: 936.9301

Ref: IN-DA003CC0