CAS 944451-28-9

[1,1′-(4R)-[4,4′-Bi-1,3-benzodioxole]-5,5′-diylbis[1,1-diphenylphosphine-κP]]dichloro[(1,2,3,4,5,6-η)-1-methyl-4-(1-methylethyl)benzene]ruthenium

Description:

The chemical substance with the name "[1,1′-(4R)-[4,4′-Bi-1,3-benzodioxole]-5,5′-diylbis[1,1-diphenylphosphine-κP]]dichloro[(1,2,3,4,5,6-η)-1-methyl-4-(1-methylethyl)benzene]ruthenium" and CAS number "944451-28-9" is a complex organometallic compound featuring a ruthenium center coordinated with various ligands. This compound is characterized by its unique structural features, including a bidentate phosphine ligand and a dioxole moiety, which contribute to its stability and reactivity. The presence of dichloro groups indicates potential for substitution reactions, making it useful in catalysis. The compound's architecture allows for specific interactions with substrates, enhancing its catalytic properties in organic transformations. Additionally, the chirality introduced by the (4R) configuration may influence its reactivity and selectivity in asymmetric synthesis. Overall, this ruthenium complex exemplifies the intricate design of organometallic compounds for applications in catalysis and materials science.

Formula: C₄₈H₄₂Cl₂O₄P₂Ru

InChI: InChI=1S/C38H28O4P2.C10H14.2ClH.Ru/c1-5-13-27(14-6-1)43(28-15-7-2-8-16-28)33-23-21-31-37(41-25-39-31)35(33)36-34(24-22-32-38(36)42-26-40-32)44(29-17-9-3-10-18-29)30-19-11-4-12-20-30;1-8(2)10-6-4-9(3)5-7-10;;;/h1-24H,25-26H2;4-8H,1-3H3;2*1H;/q;;;;+2/p-2

InChI key: InChIKey=HZLSGDCLBWZKRB-UHFFFAOYSA-L

SMILES: [Cl-][Ru+2]123456([Cl-])(C=7(C(C)C)[CH]1=[CH]2C3(C)=[CH]4[CH]57)[P](C=8C(C=9C([P]6(C%10=CC=CC=C%10)C%11=CC=CC=C%11)=CC=C%12C9OCO%12)=C%13C(=CC8)OCO%13)(C%14=CC=CC=C%14)C%15=CC=CC=C%15

Synonyms:

• (R)− RuCl[(p− Cymene)(SEGPHOS)]Cl
• Ruthenium, [1,1′-(4R)-[4,4′-bi-1,3-benzodioxole]-5,5′-diylbis[1,1-diphenylphosphine-κP]]dichloro[(1,2,3,4,5,6-η)-1-methyl-4-(1-methylethyl)benzene]-
• [1,1′-(4R)-[4,4′-Bi-1,3-benzodioxole]-5,5′-diylbis[1,1-diphenylphosphine-κP]]dichloro[(1,2,3,4,5,6-η)-1-methyl-4-(1-methylethyl)benzene]ruthenium

[RuCl(p-cymene)((R)-segphos®)]Cl

CAS: 944451-28-9

Formula: C₄₈H₄₂Cl₂O₄P₂Ru

Color and Shape: Orange to Brown to Dark red powder to crystal

Molecular weight: 916.78

Ref: 3B-R0154

Chloro[(R)-(+)-5,5'-bis(diphenylphosphino)-4,4'-bi-1,3-benzodioxole](p-cymene)ruthenium(II) chloride [RuCl(p-cymene)((R)-segphos®)]Cl

CAS: 944451-28-9

Chloro[(R)-(+)-5,5'-bis(diphenylphosphino)-4,4'-bi-1,3-benzodioxole](p-cymene)ruthenium(II) chloride [RuCl(p-cymene)((R)-segphos®)]Cl

Formula: C₄₈H₄₂ClO₄P₂RuCl

Color and Shape: yellow pwdr.

Molecular weight: 916.77

Ref: 08-44-0096

(R)RuCl[(pcymene)(SEGPHOS)]Cl

CAS: 944451-28-9

Formula: C₄₈H₄₂Cl₂O₄P₂Ru

Purity: 95%

Color and Shape: Solid

Molecular weight: 916.7682

Ref: IN-DA003C6M

Chloro[(R)-5,5'-Bis(Diphenylphosphino)-4,4'-Bi-1,3-Benzodioxole](P-Cymene)Ruthenium(II) Chloride

CAS: 944451-28-9

Chloro[(R)-5,5'-Bis(Diphenylphosphino)-4,4'-Bi-1,3-Benzodioxole](P-Cymene)Ruthenium(II) Chloride

Purity: 98%

Molecular weight: 916.77g/mol

Ref: 54-IN11833

Chloro[(R)-(+)-5,5′-bis(diphenylphosphino)-4,4′-bi-1,3-benzodioxole](p-cymene)ruthenium(II) chloride

CAS: 944451-28-9

Purity: 95%

Molecular weight: 913.07

Ref: 10-F552112