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CAS 944451-29-0

:

Chloro[(S)-(-)-5,5'-bis(diphenylphosphino)-4,4'-bi-1,3-benzodioxole](p-cymene)ruthenium(II) chloride

Description:
Chloro[(S)-(-)-5,5'-bis(diphenylphosphino)-4,4'-bi-1,3-benzodioxole](p-cymene)ruthenium(II) chloride is a coordination complex of ruthenium, characterized by its unique ligand structure and chirality. The compound features a ruthenium center coordinated to a chiral bidentate ligand derived from a bi-1,3-benzodioxole framework, which is further substituted with diphenylphosphine groups. This configuration imparts significant steric and electronic properties, making it useful in asymmetric catalysis, particularly in reactions such as hydrogenation and cross-coupling. The presence of the p-cymene moiety enhances the solubility and stability of the complex in organic solvents. The chloride ion serves as a counterion, balancing the overall charge of the complex. Due to its chiral nature, this compound can facilitate enantioselective transformations, making it valuable in the synthesis of chiral pharmaceuticals and fine chemicals. Its specific reactivity and catalytic efficiency are influenced by the steric and electronic characteristics of the ligands attached to the ruthenium center.
Synonyms:
  • (S)-RuCl[(p-Cymene)(SEGPHOS)]Cl
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