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CAS 95408-38-1

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1-Diphenylphosphino-1'-(di-tert-butylphosphino)ferrocene

Description:
1-Diphenylphosphino-1'-(di-tert-butylphosphino)ferrocene is a phosphine ligand that features a ferrocene core, which is a metallocene compound consisting of two cyclopentadienyl anions bound to a central iron cation. This compound is characterized by its unique structure, which includes two bulky di-tert-butylphosphino groups and a diphenylphosphino group, contributing to its steric and electronic properties. The presence of these phosphine groups enhances its ability to coordinate with transition metals, making it useful in various catalytic applications, particularly in organometallic chemistry and homogeneous catalysis. The bulky nature of the tert-butyl groups can provide steric hindrance, influencing the reactivity and selectivity of metal complexes formed with this ligand. Additionally, the ferrocene moiety imparts stability and redox properties, allowing for potential applications in electrochemistry. Overall, this compound exemplifies the interplay between sterics and electronics in ligand design for catalysis and material science.
Formula:C30H36FeP2
InChI:InChI=1S/C17H14P.C13H22P.Fe/c1-3-9-15(10-4-1)18(17-13-7-8-14-17)16-11-5-2-6-12-16;1-12(2,3)14(13(4,5)6)11-9-7-8-10-11;/h1-14H;7-10H,1-6H3;
SMILES:c1ccc(cc1)P(c1ccccc1)C1=CC=C[CH]1.CC(C)(C)P(C1=CC=C[CH]1)C(C)(C)C.[Fe]
Synonyms:
  • Dtbdppf
  • 1,2,3,4,5-Cyclopentanepentayl, 1-[bis(1,1-dimethylethyl)phosphino]-, compd. with 1-(diphenylphosphino)-1,2,3,4,5-cyclopentanepentayl, iron salt (1:1:1)
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