CAS 95408-45-0

1,1'-Bis(di-tert-butylphosphino)ferrocene palladium dichloride

Description:

1,1'-Bis(di-tert-butylphosphino)ferrocene palladium dichloride, with the CAS number 95408-45-0, is a coordination compound that features a palladium center coordinated to a ferrocene moiety and two di-tert-butylphosphine ligands. This compound is characterized by its robust stability and solubility in organic solvents, making it suitable for various catalytic applications, particularly in cross-coupling reactions such as Suzuki and Heck reactions. The presence of the bulky di-tert-butylphosphine ligands enhances the steric and electronic properties of the palladium center, facilitating its reactivity while minimizing side reactions. The ferrocene unit contributes to the compound's redox properties, allowing for potential applications in electrochemistry. Additionally, the dichloride form indicates that the palladium is in a +2 oxidation state, which is common for palladium complexes used in catalysis. Overall, this compound is significant in organometallic chemistry and catalysis, providing a versatile platform for synthetic transformations.

Formula: C₂₆H₄₄Cl₂FeP₂Pd

InChI: InChI=1/2C13H22P.2ClH.Fe.Pd/c2*1-12(2,3)14(13(4,5)6)11-9-7-8-10-11;;;;/h2*7-10H,1-6H3;2*1H;;/q;;;;;+2/p-2/rC26H44FeP2.2ClH.Pd/c1-23(2,3)28(24(4,5)6)21-17-13-15-19(21)27-20-16-14-18-22(20)29(25(7,8)9)26(10,11)12;;;/h13-20H,1-12H3;2*1H;/q;;;+2/p-2

SMILES: CC(C)(C)P(C1=CC=C[CH]1)C(C)(C)C.CC(C)(C)P(C1=CC=C[CH]1)C(C)(C)C.Cl.Cl.[Fe].[Pd]

Synonyms:

• [1,1'-Bis(di-tert-butylphosphino)ferrocene]dichloropalladium(II)
• Dichloro[1,1'-bis(di-t-butylphosphino)ferrocene]palladium(II)
• Dichloro[1,1'-bis(di-i-propylphosphino)ferrocene]palladium (II)
• 1,1'-Bis (di-t-butylphosphino)ferrocene palladium dichloride
• Dichloro [1,1' bis(di-tert-butylphosphino)]ferrocene palladium (II)

[1,1'-Bis(di-tert-butylphosphino)ferrocene]palladium(II) Dichloride

CAS: 95408-45-0

Formula: C₂₆H₄₄Cl₂FeP₂Pd

Purity: >98.0%(T)

Color and Shape: Orange to Amber to Dark red powder to crystal

Molecular weight: 651.75

Ref: 3B-B3160

Dichloro[1,1'-bis(di-tert-butylphosphino)ferrocene]palladium(II), Pd 16.3%

CAS: 95408-45-0

Coupling reactions, Suzuki couplings

Formula: C₂₆H₄₄Cl₂FeP₂Pd

Purity: 16.3%

Molecular weight: 651.75

Ref: 02-044829

Dichloro[1,1'-bis(di-t-butylphosphino)ferrocene]palladium(II), 99%

CAS: 95408-45-0

Dichloro[1,1'-bis(di-t-butylphosphino)ferrocene]palladium(II), 99%

Formula: (C₅H₄P(C₄H₉)₂FePdCl₂

Purity: 99%

Color and Shape: brown to purple xtl

Molecular weight: 651.75

Ref: 08-46-0445

1,1'-Bis(di-tert-butylphosphino)ferrocene palladium dichloride

CAS: 95408-45-0

Formula: C₂₆H₄₄Cl₂FeP₂Pd

Purity: 98%

Color and Shape: Solid

Molecular weight: 651.7461

Ref: IN-DA0035WI

[1,1'-Bis(di-tert-butylphosphino)ferrocene]dichloropalladium(II)

CAS: 95408-45-0

[1,1'-Bis(di-tert-butylphosphino)ferrocene]dichloropalladium(II)

Formula: C₂₆H₄₄FeP₂·Cl₂Pd

Purity: 98%

Color and Shape: very dark red powder

Molecular weight: 651.75g/mol

Ref: 54-OR55569

[1,1'-Bis(di-tert-butylphosphino)ferrocene]dichloropalladium(II)

Controlled Product

CAS: 95408-45-0

Applications [1,1'-Bis(di-tert-butylphosphino)ferrocene]dichloropalladium(II) may be used as catalyst in the Suzuki cross-coupling reaction of various aromatic and heteroaromatic halides with methyliminodiacetic acid derivatives.
References Nunes, R.J., et al.: Stud. Nat. Prod. Chem., 39, 62 (2013);

Formula: C₂₆H₄₄Cl₂FeP₂Pd

Color and Shape: Neat

Molecular weight: 651.75

Ref: TR-B416133

1,1′-Bis(di-tert-butylphosphino) ferrocene palladium chloride

CAS: 95408-45-0

Formula: C₂₆H₄₄Cl₂FeP₂Pd

Purity: 98%

Color and Shape: Solid, Crystalline Powder or Powder

Molecular weight: 651.75

Ref: 10-F044345

Dichloro[1,1'-bis(di-t-Butylphosphino)Ferrocene]Palladium(II) extrapure, 98%

CAS: 95408-45-0

Formula: C₂₆H₄₄Cl₂FeP₂P

Molecular weight: 651.7

Ref: SR-40583