CAS 95464-05-4

Dichloro[1,1′-bis(diphenylphosphino)ferrocene]palladium(II) dichloromethane adduct

Description:

Dichloro[1,1′-bis(diphenylphosphino)ferrocene]palladium(II) dichloromethane adduct, commonly referred to as Pd(dppf)Cl2·CH2Cl2, is a coordination complex featuring palladium as the central metal ion coordinated to a bidentate ligand, 1,1′-bis(diphenylphosphino)ferrocene (dppf). This compound is characterized by its distinctive ferrocene backbone, which imparts stability and unique electronic properties. The palladium center is in the +2 oxidation state, and the dichloromethane adduct indicates the presence of dichloromethane as a solvent molecule associated with the complex. This compound is typically used as a catalyst in various organic reactions, particularly in cross-coupling reactions such as the Suzuki and Stille reactions, due to its ability to facilitate the formation of carbon-carbon bonds. Its properties include good solubility in organic solvents and thermal stability, making it a valuable reagent in synthetic chemistry. The presence of phosphine ligands enhances its reactivity and selectivity in catalytic processes.

Formula: C₃₄H₂₈Cl₂FeP₂Pd·CH₂Cl₂

InChI: InChI=1S/2C17H14P.CH2Cl2.2ClH.Fe.Pd/c2*1-3-9-15(10-4-1)18(17-13-7-8-14-17)16-11-5-2-6-12-16;2-1-3;;;;/h2*1-14H;1H2;2*1H;;/q2*-1;;;;2*+2/p-2

InChI key: InChIKey=SNRCKKQHDUIRIY-UHFFFAOYSA-L

SMILES: [Cl-][Pd+2]1([Cl-])[P]([C-]23[Fe+2]456789%10([C-]%11([CH]4=[CH]5[CH]6=[CH]7%11)[P]1(C%12=CC=CC=C%12)C%13=CC=CC=C%13)[CH]2=[CH]8[CH]9=[CH]%103)(C%14=CC=CC=C%14)C%15=CC=CC=C%15.C(Cl)Cl

Synonyms:

• (1,1′-Bis(diphenylphosphino)ferrocene)dichloropalladium-dichloromethane (1:1)
• Bis (diphenylphosphion) ferrocene palladium (II) dichloromethane
• Dichloro[1,1'-bis(diphenylphosphino)ferrocene]palladium(II) dichloromethane adduct
• Ferrocene, 1,1′-bis(diphenylphosphino)-, palladium complex
• Methane, dichloro-, compd. with (SP-4-2)-[1,1′-bis(diphenylphosphino)ferrocene-P,P′]dichloropalladium (1:1)
• Palladium, [1,1′-bis(diphenylphosphino)ferrocene-P,P′]dichloro-, (SP-4-2)-, compd. with dichloromethane (1:1)
• Palladium, [1,1′-bis(diphenylphosphino-κP)ferrocene]dichloro-, (SP-4-2)-, compd. with dichloromethane (1:1)
• Pd(dppf)2Cl2
• PdCl₂(dppf)·CH₂Cl₂
• [1,1'-Bis(diphenylphosphino)ferrocene]palladium(II) chloride,complex with dichloromethane
• [1,1′-Bis(diphenylphosphino)ferrocene]dichloropalladium(II) dichloromethane complex
• [1,1′-Bis(diphenylphosphino)ferrocene]palladium dichloride dichloromethane adduct
• [1,1′-Bis(diphenylphosphino)ferrocene]palladium dichloride methylene chloride adduct

1,1'-Bis(diphenylphosphino)ferrocene-palladium(II)dichloride dichloromethane complex

CAS: 95464-05-4

Formula: C₃₅H₃₀Cl₄FeP₂Pd

Purity: 98%

Color and Shape: Solid

Molecular weight: 816.6372

Ref: IN-DA0032HX

[1,1'-Bis(diphenylphosphino)ferrocene]palladium(II) Dichloride Dichloromethane Adduct

CAS: 95464-05-4

Formula: C₃₄H₂₈Cl₂FeP₂Pd·CH₂Cl₂

Purity: >98.0%(T)

Color and Shape: Light yellow to Amber to Dark green powder to crystal

Molecular weight: 816.64

Ref: 3B-B2064

Dichloro 1,1'-bis(diphenylphosphino)ferrocene palladium (II) dichloromethane, 99%

CAS: 95464-05-4

Dichloro 1,1'-bis(diphenylphosphino)ferrocene palladium (II) dichloromethane, 99%

Formula: (C₅H₄P(C₆H₅)₂FePdCl₂·CH₂Cl₂

Purity: 99%

Color and Shape: orange-red pwdr.

Molecular weight: 731.77 (816.65)

Ref: 08-46-0450

[1,1'-Bis(diphenylphosphino)ferrocene]palladium(II) chloride dichloromethane complex

CAS: 95464-05-4

[1,1'-Bis(diphenylphosphino)ferrocene]palladium(II) chloride dichloromethane complex

Formula: C₃₄H₂₈FeP₂·2Cl₂Pd

Purity: ≥95%

Color and Shape: red crystalline solid

Molecular weight: 909.03g/mol

Ref: 54-OR40417

(1,1''-Bis(diphenylphosphino)ferrocene)palladium(II) dichloride, complex with Dichloromethane

CAS: 95464-05-4

Formula: (C₁₇H₁₄P)₂Fe·PdCl₂

Purity: (Pd) ≥ 12.0%

Color and Shape: Orange to red crystalline powder

Molecular weight: 731.70

Ref: 7W-GK7338

PdCl2(dppf)·CH2Cl2 (HPMC encapsulated)

CAS: 95464-05-4

Formula: C₃₄H₂₈Cl₂FeP₂Pd·CH₂Cl₂

Color and Shape: White to Light red capsule

Molecular weight: 816.64

Ref: 3B-R0307

1,1′-Bis(Diphenylphosphino)ferrocene-palladium(II)dichloride dichloromethane complex

CAS: 95464-05-4

Formula: C₃₅H₃₀Cl₄FeP₂Pd

Purity: 98.0%

Color and Shape: Solid, Crystalline Powder or Powder

Molecular weight: 816.64

Ref: 10-F048593

Dichloro[1,1''-ferrocenylbis(diphenylphosphine)]palladium(II)dichloromethane adduct

CAS: 95464-05-4

Formula: C₅H₄P(C₆H₅)₂FePdCl₂·CH₂Cl₂

Molecular weight: 816.65

Ref: 7W-GX3273

(1,1'-Bis(diphenylphosphino)ferrocene)dichloropalladium-dichloromethane

Controlled Product

CAS: 95464-05-4

Stability Light Sensitive
Applications (1,1'-Bis(diphenylphosphino)ferrocene)dichloropalladium-dichloromethane is used in the preparation of imidazoles, benzimidazoles, and tetrahydropyrimidines.
References Geden, J. et al.: J. Org. Chem., 78, 4158 (2013);

Formula: C₃₄H₂₈Cl₂FeP₂Pd·CH₂Cl₂

Color and Shape: Neat

Molecular weight: 816.64

Ref: TR-B430360

[1,1'-Bis(diphenylphosphino)ferrocene]-dichloropalladium (II) dichloromethane complex

Controlled Product

CAS: 95464-05-4

1,1'-Bis(diphenylphosphino)ferrocene]-dichloropalladium (II) dichloromethane complex is a fine chemical that is used as a scaffold for the synthesis of other compounds. It can be used as a building block to make other chemicals or as an intermediate in chemical reactions. It is also a versatile research chemical and is used to make speciality chemicals. 1,1'-Bis(diphenylphosphino)ferrocene]-dichloropalladium (II) dichloromethane complex has high quality and is a useful building block for making other compounds.

Formula: C₃₅H₃₀Cl₄P₂PdFe

Purity: Min. 95%

Color and Shape: Red Powder

Molecular weight: 816.64 g/mol

Ref: 3D-FB31909