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CAS 99326-34-8

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Bis(1,5-cyclooctadiene)rhodium(I) trifluoromethanesulfonate

Description:
Bis(1,5-cyclooctadiene)rhodium(I) trifluoromethanesulfonate, with the CAS number 99326-34-8, is a coordination complex of rhodium that features two 1,5-cyclooctadiene ligands and a trifluoromethanesulfonate counterion. This compound is characterized by its distinctive rhodium(I) oxidation state, which is crucial for its reactivity in various catalytic processes, particularly in organic synthesis. The presence of the cyclooctadiene ligands provides a stable, planar coordination environment around the rhodium center, enhancing its ability to participate in catalytic cycles. The trifluoromethanesulfonate group, known for its strong electron-withdrawing properties, contributes to the overall stability and solubility of the complex in polar solvents. This compound is often utilized in catalysis, including hydroformylation and other reactions involving the activation of alkenes. Its unique structural and electronic properties make it a valuable reagent in synthetic organic chemistry, particularly in the development of new catalytic methodologies.
Formula:C17H24F3O3RhS
InChI:InChI=1/2C8H12.CHF3O3S.Rh/c2*1-2-4-6-8-7-5-3-1;2-1(3,4)8(5,6)7;/h2*1-2,7-8H,3-6H2;(H,5,6,7);/p-1/b2*2-1-,8-7-;;
SMILES:C1=CCCC=CCC1.C1=CCCC=CCC1.C(F)(F)(F)S(=O)(=O)[O-].[Rh]
Synonyms:
  • (1Z,5Z)-cycloocta-1,5-diene
  • Rhodium
  • Trifluoromethanesulfonate
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