Organoboranes

<p>Applications Triisopropyl Borate is a borate ester used in Suzuki couplings.<br> Not a dangerous good if item is equal to or less than 1g/ml and there is less than 100g/ml in the package<br>References Wolfe, J. et al.: J. Am. Chem. Soc., 121, 9550 (1999); Darses, S. et al.: Eur. j. Org. Chem., 8, 1875<br></p>

<p>Applications Ethyl [(tert-Butyldimethylsilyl)oxy]acetate (cas# 67226-78-2) is a compound useful in organic synthesis.<br></p>

<p>Applications 1,​2-​Bis(trimethylsiloxy)​ethane is an organic reagent, used in the preparation of nonracemic hexahydrofurapyranol which acts as a high-affinity ligand for HIV-1 protease inhibitors.<br> Not a dangerous good if item is equal to or less than 1g/ml and there is less than 100g/ml in the package<br>References Ghosh, A. et al.: Tetra. Lett., 58, 3230 (2017)<br></p>

<p>Applications Trimethylboroxin is used in a diverse array of areas, including as a polymerization additive. Trimethylboroxin is also used in the preparation of CBS catalysts for asymmetric reductions.<br> Not a dangerous good if item is equal to or less than 1g/ml and there is less than 100g/ml in the package<br>References Gilmore, N., et al.: Tetrahedron Asy., 14, 2115 (2003); Najera, C., et al.: Adv. Synth. Catal., 346, 1798 (2004);<br></p>

<p>Applications Tris(trimethylsilyl)silane) is used in the synthesis of silated alkenes and alkynes. Also used in the preparation of fused quinolines.<br> Not a dangerous good if item is equal to or less than 1g/ml and there is less than 100g/ml in the package<br>References Kopping, B.et al.: J. Org. Chem., 57, 3994 (1992); Du, W. et al.: Org. Lett., 5, 1765 (2003);<br></p>

<p>Applications Tetrabutylammonium Borohydride is a strong reducing agent used in the synthesis of hyperbranched polyglycerol grafting on the surface of silica-coated nanoparticles.<br>References Panja, P. et al.: ACS Sust. Chem. Eng., 5, 4879 (2017);<br></p>

<p>Applications rac 1-O-Trimethylsilyl 3-Chloro-1,2-propanediol (cas# 1246820-26-7) is a compound useful in organic synthesis.<br></p>

<p>Applications [3-[(Trimethylsilyl)oxy]-2-cyclohexen-1-yl]-benzene (cas# 108643-81-8) is a compound useful in organic synthesis.<br></p>

<p>Stability Volatile<br>Applications Hexamethyldisilane is an organic silylating and disilylating reagent. It is also a useful reagent for reductive coupling, reductive deuteration, aroylarylation, carbosilylation, insertion, deuteration and dimerization reactions.<br>References Xiao, G., et al.: Tetrahedron Lett., 59, 1836 (2018); Lu, A., et al.: Angew. Chem. Int. Ed., 57, 3233 (2018); Deb, M., et al.: New J. Chem., 41, 14528 (2017); Hiyama, T., et al.: e-EROS Encyclopedia of Reagents for Organic Synthesis, 1 (2010)<br></p>

<p>Applications 3-(Dimethylphenylsilyl)-cyclobutanone is an intermediate used in synthesizing 2-Cyclobutenyl-3-trifluoromethyl-5-chloro-1H-indole-1-carboxylic Acid Ethyl Ester, which is synthesized from 5-chloro-2-oxindole (C375030), that is used in the preparation of novel GSK-3β inhibitors as anticancer agents.<br>References Choi, M.J., et al.: Bull. Korean. Chem. Soc., 32, 2015 (2011); Otani, M., et al.: Bioorg. Med. Chem. Lett.. 20, 4259 (2010); Jhan, Y.H., et al.: Tetrahedron. Lett., 54, 1155 (2013); Hsieh, J.C., et al.: Org. Biomolec. Chem., 10, 6404 (2012);<br></p>

<p>Applications TRIPHENYLSILANE (cas# 789-25-3) is a useful research chemical.<br></p>

<p>Applications N-(Methoxymethyl)-N-[(trimethylsilyl)methyl]benzenemethanamine is used in the synthesis of pyrrolidine derivatives as novel sodium channel blockers used to treat ischemic related ailments.<br>References Seki, M. et al.: Bioorg. Med. Chem. Lett., 23, 4230 (2013);<br></p>

<p>Applications Allenylboronic acid pinacol ester<br></p>

<p>Stability Hygroscopic, Light-sensitive<br>Applications Triphenylmethylium Tetrafluoroborate is reagent used in organic synthesis such as the direct synthesis of 1,1-diphenyl-3-arylindanes.<br>References Surapanich, N. et al.: Synlett., 27, 2689 (2016);<br></p>

<p>Stability Moisture Sensitive<br>Applications Chlorotriethoxysilane (cas# 4667-99-6) is a useful research chemical.<br></p>

<p>Stability Moisture Sensitive<br>Applications Tert-Butyldimethylsilyl Trifluoromethanesulfonate is a highly reactive silylating agent and lewis acid capable of converting primary, secondary and tertiary alcohols to their respectctive TBDMS. Tert-Butyldimethylsilyl Trifluoromethanesulfonate is also used to covert ketones and lactones into their enol silyl ethers.<br> Not a dangerous good if item is equal to or less than 1g/ml and there is less than 100g/ml in the package<br>References Hua, D.H. et al.: e-ROS Encyc. Reag. Org. Synth., No pp. given (2001); Suzuki, T. et al.: Synthesis, 4, 555 (2001);<br></p>

<p>Applications 1,3-Bis(tert-Butyldimethylsiloxy)-2-propanol is an intermediate in the synthesis of 2-Linoleoyl-rac-glycerol (L467960), which is a atty acid monoglycerides in vegetable oils with medium unsaturation.<br>References Compton, D., et al.: J. Pharmacol. Exp. Ther., 277, 586 (1996), Devane, W., et al.: Science, 258, 1946 (1992),<br></p>

<p>Applications Tetraethylammonium Tetrafluoroborate is used in the preparation of some organic salts of fluoboric acids.<br>References Wilke-D., et al.: Ber. Dtsch Chem. Ges.; 60B, 115 (1927)<br></p>

<p>Applications N,N-Diethyl(trimethylsilyl)amine is a chemical reagent with wide application in organic chemistry. Used in stereospecific addition reactions as well as in SN2 nucleophilic substitutions.<br> Not a dangerous good if item is equal to or less than 1g/ml and there is less than 100g/ml in the package<br>References Bassindale, A. et al.: J. Organometal. Chem., 667, 66 (2003); Hagiwara, H. et al.: J. Chem. Soc., Perk Trans., 3, 316 (2002);<br></p>

<p>Applications (1-Ethoxycyclopropoxy)trimethylsilane used as a reactant in the synthesis of di-, tri- and tetracyclopropylhydrazines. Also used as reagent in the synthesis of g elsemoxonine which is found in gelsemium plant species that is used in traditional asian medicine.<br> Not a dangerous good if item is equal to or less than 1g/ml and there is less than 100g/ml in the package<br>References Shestakov, A., et al.: Chem. Commun., 52, 2398 (2016); Diethelm, S., et al.: J. Am. Chem. Soc., 137, 6084 (2015);<br></p>

<p>Applications (2-Cyclobuten-1-yldimethylsilyl)benzene is an intermediate used in synthesizing 2-Cyclobutenyl-3-trifluoromethyl-5-chloro-1H-indole-1-carboxylic Acid Ethyl Ester, which is synthesized from 5-chloro-2-oxindole (C375030), that is used in the preparation of novel GSK-3β inhibitors as anticancer agents.<br>References Choi, M.J., et al.: Bull. Korean. Chem. Soc., 32, 2015 (2011); Otani, M., et al.: Bioorg. Med. Chem. Lett.. 20, 4259 (2010); Jhan, Y.H., et al.: Tetrahedron. Lett., 54, 1155 (2013); Hsieh, J.C., et al.: Org. Biomolec. Chem., 10, 6404 (2012);<br></p>

<p>Applications 3-[[(1,1-Dimethylethyl)diphenylsilyl]oxy]-1,2-propanediol is an intermediate in the synthesis of 1,2-Dioleoyl-rac-glycerol (D482175), which is an analog of 1,3-Dioleoylglycerol (D484210) which is used in the synthesis of amphiphilic gadolinium complexes as MRI contrast agents.<br>References Accardo, A., et. al.: J. Mater. Chem. B., 1, 617 (2013)<br></p>

<p>Applications Tetrakis(acetonitrile)palladium Bis(tetrafluoroborate) is used to prepare an α-Diimine-transition metal complex, which is used as a catalyst for polymerization of olefins. It is also a catalyst used in cross coupling reaction for C-C, C-O, and C-N bond formation.<br>References Feldman, J., et al.: Organometallics, 16, 1514 (1997); Johnson, L., et al.: PCT Int. Appl., WO 9623010 A2 19960801 (1996); Poppenbery, J., et al.: Surface Sci., 2011; Pijnenburg, N., et al.: Dalton Transactions, 40, 8896 (2011); Kilpin, K., et al.: Inorg. Chem., 50, 6334 (2011)<br></p>

<p>Stability Moisture Sensitive<br>Applications N-Trimethylsilylacetamide is a silylating agent used in organic synthesis. N-Trimethylsilylacetamide is used in the preparation of the antibacterial agent Cefdinir (C242670).<br>References Takano, R. et al.: J. Carb. Chem., 14, 885 (1995); Rao, K. et al.: Synth. Comm., 37, 2275 (2007);<br></p>

<p>Applications 3-[(tert-Butyldimethylsilyl)oxy]-1-propanol (cas# 73842-99-6) is a compound useful in organic synthesis.<br></p>

<p>Stability Moisture Sensitive and Hygroscopic<br>Applications Triethylsilyl Trifluoromethanesulfonate is a reagent used in the synthesis of pharmaceuticals such as cocosolide, an immunosuppressive agent.<br> Not a dangerous good if item is equal to or less than 1g/ml and there is less than 100g/ml in the package<br>References Gunasekera, S. et al.: Chem. Eur. J., 22, 8158 (2016);<br></p>