Allylpalladium(II) chloride dimer, Pd 56.0% min

CAS: 12012-95-2

Ref. 02-010005

Product Information

• Name: Allylpalladium(II) chloride dimer, Pd 56.0% min
• Synonyms: Allyl Palladium (Ii) Chloride Dimer, Allylchloropalladium dimer, Allylpalladium chloride, Allylpalladium chloride dimer, Allylpalladium(II) chloride dimer, Bis((η3-allyl)(chloro)palladium), Bis((η³-allyl)(chloro)palladium), Bis((μ-chloro)(2-propenyl)palladium), Bis(allyl(μ-chloro)palladium), Bis(allyl)dichlorodipalladium, Bis(allylchloropalladium), Bis(chloro(η3-2-propenyl)palladium), Bis(chloro(η³-2-propenyl)palladium), Bis(chloro(π-propenyl)palladium), Bis(chloro-π-allylpalladium), Bis(η3-allyl)bis(μ-chloro)dipalladium, Bis(η3-allyl)dichlorodipalladium, Bis(η³-allyl)bis(μ-chloro)dipalladium, Bis(η³-allyl)di(μ-chloro)dipalladium, Bis(η³-allyl)dichlorodipalladium, Bis(μ-chloro)bis(η3-2-propenyl)dipalladium, Bis(μ-chloro)bis(η³-2-propenyl)dipalladium, Bis(π-allyl)dichlorodipalladium, Bis(π-allylpalladium chloride), Bis(π-allylpalladium) dichloride, Bis[(η3-allyl)-μ-chloropalladium], Bis[(η³-allyl)-μ-chloropalladium], Bis[(π-allyl)chloropalladium], Bis[chloro(η3-allyl)palladium], Bis[chloro(η³-allyl)palladium], Bis[μ-chloro(η3-2-propenyl)palladium], Bis[μ-chloro(η³-2-propenyl)palladium], Chloropalladium(1+) Prop-2-En-1-Ide (1:1), Di-Μ-Cloro-Bis(Η-Alil)Paladio, Di-μ-chlor-bis(η-allyl)palladium, Di-μ-chlorobis((η3-allyl)palladium), Di-μ-chlorobis((η³-allyl)palladium), Di-μ-chlorobis(allylpalladium), Di-μ-chlorobis(η3-2-propenyl)dipalladium, Di-μ-chlorobis(η3-allyl)dipalladium, Di-μ-chlorobis(η³-2-propenyl)dipalladium, Di-μ-chlorobis(η³-allyl)dipalladium, Di-μ-chlorobis(π-allyl)dipalladium, Di-μ-chlorodi-π-allyldipalladium, Di-π-Allylpalladium chloride, Di-π-allyldi-μ-chlorodipalladium, Diallyldichlorodipalladium, Diallyldipalladium dichloride, Dichloroniopalladium, Palladium, Prop-1-Ene, Nsc 151255, Palladium allyl chloride, Palladium, di-μ-chlorobis(η3-2-propenyl)di-, Palladium, di-μ-chlorobis(η³-2-propenyl)di-, Palladium, di-π-allyldi-μ-chlorodi-, Palladium, dichlorodi-π-allyldi-, π-Allyl palladium chloride, π-Allylpalladium chloride dimer, π-Allylpalladium(II) chloride dimer

Description

Allylpalladium(II) chloride dimer is used as an important catalyst in Heck reaction. It reacts with cyclopentadienyl anion to give cyclopentadienyl allyl palladium. It acts as a precatalyst for asymmetric and cross-coupling catalysis. Further, it is used in the preparation of 1,4-diallyl-1,2-dihydroisoquinolines. It is also employed as a catalyst for greener Buchwald-Hartwig coupling reaction and involved in the synthesis of cationic palladium catalysts. In addition, it takes part in preparation of -heterocyclic carbene-palladium-eta3-allyl chloride complex, which is an efficient catalyst for the Suzuki-Miyaura cross-coupling reactions in synthetic chemistry. This Thermo Scientific Chemicals brand product was originally part of the Alfa Aesar product portfolio. Some documentation and label information may refer to the legacy brand. The original Alfa Aesar product / item code or SKU reference has not changed as a part of the brand transition to Thermo Scientific Chemicals.

• Brand: Alfa Aesar By Thermo Fisher Scientific

Chemical properties

• Molecular weight: 365.89
• Formula: C₆H₁₀Cl₂Pd₂
• InChI key: PENAXHPKEVTBLF-UHFFFAOYSA-L