1,5-Cyclooctadiene(pyridine)(tricyclohexylphosphine)iridium(I) hexafluorophosphate, 99%

CAS: 64536-78-3

Ref. 02-042057

Product Information

• Name: 1,5-Cyclooctadiene(pyridine)(tricyclohexylphosphine)iridium(I) hexafluorophosphate, 99%
• Synonyms: crabtree's catalyst, (1,5-Cyclohexadiene)pyridine(tricyclohexylphosphine)iridium hexafluorophosphate, (1,5-Cyclooctadiene)(pyridine)(tricyclohexylphosphine)iridium(1+) hexafluorophosphate, (1,5-Cyclooctadiene)(pyridine)(tricyclohexylphosphine)iridium(I) hexafluorophosphate, (1,5-Cyclooctadiene)pyridine(tricyclohexylphosphine)iridium hexafluorophosphate, (1,5-cyclooctadiene)(pyrid.)(tric.hexyl-phosphine)irid(I)pf6, (Tricyclohexyphosphine)(1,5-cyclooctadiene)(pyridine)iridium(I) hexafluorophosphate, (η⁴-1,5-Cyclooctadiene)(pyridine)(tricyclohexylphosphine)iridium(I) hexafluorophosphate, 1,5-Cyclooctadiene, iridium complex, Crabtree'S Catalyst, Crabtrees Catalyst, Felkin-Crabtree catalyst, Iridium(1+), [(1,2,5,6-η)-1,5-cyclooctadiene](pyridine)(tricyclohexylphosphine)-, hexafluorophosphate(1-), Iridium(1+), [(1,2,5,6-η)-1,5-cyclooctadiene](pyridine)(tricyclohexylphosphine)-, hexafluorophosphate(1-) (1:1), Phosphate(1-), hexafluoro-, [(1,2,5,6-η)-1,5-cyclooctadiene](pyridine)(tricyclohexylphosphine)iridium(1+), Phosphine, tricyclohexyl-, iridium complex, [(1,2,5,6-η)-1,5-Cyclooctadiene](pyridine)(tricyclohexylphosphine)iridium(1+) hexafluorophosphate(1-)

Description

1,5-Cyclooctadiene(pyridine)(tricyclohexylphosphine)iridium(I) hexafluorophosphate is used as a catalyst for hydrogenation of mono-, di-, tri-, and tetra-substituted substrates and the isomerization and hydroboration of alkenes. It is also used in isotope exchange reactions, especially the direct exchange of a hydrogen atom with its isotopes deuterium and tritium. Carbonyl groups are also known to direct the hydrogenation by the Crabtree catalyst is highly regioselective. This Thermo Scientific Chemicals brand product was originally part of the Alfa Aesar product portfolio. Some documentation and label information may refer to the legacy brand. The original Alfa Aesar product / item code or SKU reference has not changed as a part of the brand transition to Thermo Scientific Chemicals.

• Brand: Alfa Aesar By Thermo Fisher Scientific

Chemical properties

• Molecular weight: 804.90
• Formula: C₃₁H₅₀F₆IrNP₂
• Purity: 99%
• Color/Form: Powder, Orange
• InChI key: UJXHUUQZACSUOG-KJWGIZLLSA-N