Di-^m-bromobis(tri-tert-butylphosphine)dipalladium(I)

CAS: 185812-86-6

Ref. 02-044446

Product Information

• Name: Di-^m-bromobis(tri-tert-butylphosphine)dipalladium(I)
• Synonyms: bis(tri-tert-butyl-λ⁵-phosphanyl)cyclodipalladabromane, Di-Bromobis(Tri-T-Butylphosphino)Dipalladium (I), Palladium (I) Tri-Tert-Butylphosphine Bromide, Dimer, Bromo(tri-tert-butylphosphine)palladium(I)dimer, Di--Bromobis(Tri-Tert-Butylphosphino)Dipalladium(I), Di-mu-bromobis(tri-t-butylphosphino)dipalladium(I), Dibromobis(tri-tert-butylphosphine)dipalladium, Dibromobis(tri-tert-butylphosphine)dipalladium(I), Bromopalladium, Tritert-Butylphosphane

Description

Coupling reactions. Will activate aryl chloride and sterically hindered or electron rich aryl/vinyl bromides and iodides. Especially active in difficult aminations.Di-μ-bromobis(tri-tert-butylphosphine)dipalladium(I) is used as a catalyst for Suzuki coupling, Negishi coupling and Buchwald-hartwig amination reactions. It is used as a catalyst for C-C, C-N and C-S bond formation, gamma-arylation of alfa,beta-unsaturated esters and diastereoselective arylation of 4-substituted cyclohexyl esters. It is also involved in aromatic halide substitution reactions. This Thermo Scientific Chemicals brand product was originally part of the Alfa Aesar product portfolio. Some documentation and label information may refer to the legacy brand. The original Alfa Aesar product / item code or SKU reference has not changed as a part of the brand transition to Thermo Scientific Chemicals.

• Brand: Alfa Aesar By Thermo Fisher Scientific

Chemical properties

• Molecular weight: 779.31
• Formula: C₂₄H₅₆Br₂P₂Pd₂
• Color/Form: Crystals or crystalline powder, Dark green or greenish-blue
• InChI key: JWWUTWDBVLEWDQ-UHFFFAOYSA-P