Chlorobis(cyclooctene)iridium(I) dimer, Ir nominally 42.9%

CAS: 12246-51-4

Ref. 02-044966

Product Information

• Name: Chlorobis(cyclooctene)iridium(I) dimer, Ir nominally 42.9%
• Synonyms: chlorobis(cyclooctene)iridium dimer, (7Z)-cyclooctene, 2,2,4,4-Tetramethyl-1$L3,3$L3-Dichlora-2$L4,4$L4-Diiridacyclobutane, Bis((μ-chloro)bis(cyclooctene)iridium), Bis(Cyclooctene)Iridium(I) Chloride, Dimer, Bis(chlorobis(cyclooctene)iridium), Bis(cyclooctene)iridium chloride dimer, Bis(cyclooctene)iridium(I) chloride, Bis(μ-chloro)bis(bis(cyclooctene)iridium), Bis(μ-chloro)tetrakis(cyclooctene)diiridium, Bis[chlorobis(η²-cyclooctene)iridium], Chlorobis(cyclooctene)iridium dimer, Chlorobis(cyclooctene)iridium(I), Cyclooctene, iridium complex, Di-μ-Chlorotetrakis(cyclooctene)diiridium, Di-μ-chlorotetrakis(η²-cyclooctene)diiridium, Di-μ-chlorotetrakis[(1,2-η)-cyclooctene]diiridium, Dichlorotetrakis(cyclooctene)diiridium, Iridium, di-μ-chlorotetrakis[(1,2-η)-cyclooctene]di-, Tetrakis(η²-cyclooctene)dichlorodiiridium, [IrCl(COE)2]2

Description

Chlorobis(cyclooctene)iridium(I) dime is used as catalyst for Isomerization-hydroboration reactions with nido-carboranyldiphosphine as stabilizing ligand, Hydrogen peroxide oxidation of hydroxamic acids and their subsequent hetero Diels-Alder cycloaddition reactions, Immobilization of organic functional groups onto solid supports through vinylsilane coupling reactions, Alkylation reactions, Guerbet reaction, Allylic amination reactions in a DNA-diene-iridium(I) hybrid system, Asymmetric hydroamination reactions. This Thermo Scientific Chemicals brand product was originally part of the Alfa Aesar product portfolio. Some documentation and label information may refer to the legacy brand. The original Alfa Aesar product / item code or SKU reference has not changed as a part of the brand transition to Thermo Scientific Chemicals.

• Brand: Alfa Aesar By Thermo Fisher Scientific

Chemical properties

• Molecular weight: 896.14
• Formula: C₃₂H₅₆Cl₂Ir₂
• InChI key: CJJIQMGSHWWMCK-UHFFFAOYSA-L