Methoxy(cyclooctadiene)iridium(I) dimer, Ir nominally 58%

CAS: 12148-71-9

Ref. 02-044967

Product Information

• Name: Methoxy(cyclooctadiene)iridium(I) dimer, Ir nominally 58%
• Synonyms: bis(1,5-cyclooctadiene, (Z,Z)-); bis(methoxyiridiumylium), (1,5-Cyclooctadiene)(methoxy)iridium(I) dimer, (1,5-Cyclooctadiene)methoxyiridium dimer, (1Z,5Z)-cycloocta-1,5-diene, -methoxy)iridium(I) dimer, 1,2,2,3,4,4-Hexamethyl-1$L3,3$L3-Dioxa-2$L4,4$L4-Diiridacyclobutane, 1,5 Cyclooctadiene(Μ, 1,5-Cyclooctadiene, iridium complex, Bis((1,5-cyclooctadiene)(μ-methanolato)iridium), Bis(1,5-cyclooctadiene)-di-μ-methoxodiiridium, Bis(1,5-cyclooctadiene)di-μ-methoxydiiridium, Bis(1,5-cyclooctadiene)di-μ-methoxydiiridium(I), Bis(1,5-cyclooctadiene)dimethoxydiiridium, Bis(cyclooctadiene(methoxy)iridium), Bis(η⁴-1,5-cyclooctadiene)-di-μ-methoxodiiridium, Bis[(1,2,5,6-η)-1,5-cyclooctadiene]di-μ-methoxydiiridium, Bis[(1,5-cyclooctadiene)(methanolato)iridium], Bis[(1,5-cyclooctadiene)(methoxy)iridium], Di-μ-methoxobis(1,5-cyclooctadiene)diiridium, Di-μ-methoxobis(1,5-cyclooctadiene)diiridium(I), Di-μ-methoxobis(1,5-cyclooctadiene)diiridium(I), min. 98%, Iridium, bis[(1,2,5,6-η)-1,5-cyclooctadiene]di-μ-methoxydi-, Iridium, dimethoxybis(1,5-cyclooctadiene)di-, Methoxy(cyclooctadiene)iridium(I) dimer

Description

Methoxy(cyclooctadiene)iridium(I) dimer is used as a catalyst in the preparation of heteroaryl fused indole ring systems and borylation and Suzuki-miyaura coupling. Further, it is used in tetraborylation reactions, ortho-silylation of aryl ketone, benzaldehyde and benzyl alcohol derivatives through C-H activation. The most useful application is highly regio and enantio selection asymmetric hydroboration. This Thermo Scientific Chemicals brand product was originally part of the Alfa Aesar product portfolio. Some documentation and label information may refer to the legacy brand. The original Alfa Aesar product / item code or SKU reference has not changed as a part of the brand transition to Thermo Scientific Chemicals.

• Brand: Alfa Aesar By Thermo Fisher Scientific

Chemical properties

• Molecular weight: 662.87
• Formula: C₁₈H₃₀Ir₂O₂
• InChI key: SGBSCFWMCJNCRM-MIXQCLKLSA-N