18-Crown-6, 99%

CAS: 17455-13-9

Ref. 02-A11249

Product Information

• Name: 18-Crown-6, 99%
• Synonyms: 1,4,7,10,13,16-Hexaoxacyclooctadecane, 1,4,7,10,13,16-Hexaoxaciclooctadecano, 1,4,7,10,13,16-Hexaoxacyclooctadecan, 18-Crown ether-6, 18-Crown-6-ether, Coronand 18C6, Crown Ether O 18, Crown Ether/18-Crown-6, Crownwhitextl, Ethylene oxide cyclic hexamer, Nsc 159836

Description

18-Crown-6 is used as an efficient phase transfer catalyst and as a complexing agent with a variety of small cation. It is involved in the synthesis of diaryl ethers, diaryl thioethers, and diarylamines mediated by potassium fluoride-alumina and 18-crown-6. It facilitates the solubility of potassium permanganate in benzene, which is used for oxidizing the organic compounds. It is used to accelerate various substitution reactions as well as enhances the power of nucleophiles such as potassium acetate. It is utilized in the alkylation reactions in the presence of potassium carbonate, N-alkylation of glutarimide and succinimide with dimethylcarbonate. The complex formed by its reaction with potassium cyanide acts as a catalyst in the cyanosilylation of aldehydes, ketones and quinines with trimethylsilyl cyanide (TMSCN). This Thermo Scientific Chemicals brand product was originally part of the Alfa Aesar product portfolio. Some documentation and label information may refer to the legacy brand. The original Alfa Aesar product / item code or SKU reference has not changed as a part of the brand transition to Thermo Scientific Chemicals.

• Brand: Alfa Aesar By Thermo Fisher Scientific

Chemical properties

• Molecular weight: 264.32
• Formula: C₁₂H₂₄O₆
• Purity: 99%
• Color/Form: Crystals or powder or crystalline powder or fused/lumpy solid or liquid as melt, Clear, colorless or white
• InChI: InChI=1S/C12H24O6/c1-2-14-5-6-16-9-10-18-12-11-17-8-7-15-4-3-13-1/h1-12H2
• InChI key: InChIKey=XEZNGIUYQVAUSS-UHFFFAOYSA-N
• SMILES: C1COCCOCCOCCOCCOCCO1