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Phenoxyacetyl chloride, 98%
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Alfa Aesar By Thermo Fisher Scientific logo

Phenoxyacetyl chloride, 98%

CAS: 701-99-5

Ref. 02-A13761

50g
73.00 €
250gTo inquire
Estimated delivery in United States, on Thursday 21 Nov 2024

Product Information

Name:
Phenoxyacetyl chloride, 98%
Synonyms:
  • 2-phenoxyacetyl chloride
  • 2-Phenoxyacetyl chloride
  • Acetyl chloride, 2-phenoxy-
  • Acetyl chloride, phenoxy-
  • Acetylchloride,phenoxy-
  • Acyl chloride kind
  • Akos Bbs-00003927
  • Chlorure de phenoxyacetyle
  • Cloruro De Fenoxiacetilo
  • Labotest-Bb Lt00643586
  • See more synonyms
  • Nsc 9808
  • Phenoxy-Acetylchlorid
  • Phenoxyacetic acid chloride
  • Phenoxyacetylchlorid
  • Phenoxyethanoyl chloride
  • Phenyloxyacetyl chloride
Description:

Acylation of D- and DL-WV with phenoxyacetyl chloride, followed by cleavage of the t-butyl ester,afforded the penultimate penicilloic acids. Phenoxyacetyl chloride was used in the synthesis of series of macrocyclic bis-β-lactams, 5-phenyl-6-epiphenoxymethylpenicillin benzyl ester, N-protected guanosine derivatives, useful in RNA synthesis, phenyloxyketene, for cycloaddition to imines leading to β-lactams. Treatment of iminophosphoranes with phenoxyacetyl chloride afforded respectively the trans- and cis-3-(acylamino)-p-lactams. By the oxidative addition of stannous fluoride to allyliodide, with 1, 2-O-isopropylidene-D-glyceraldehyde and phenoxyacetyl chloride results in the predominant formation of erythro homoallylester, which is in turn converted into 2-deoxy-D-ribose. The 4-disubstituted P-lactams (4a-c and 6a-b) were prepared through the reaction of N,N-diphenylhydrazones and N-methyl-N-phenylhydrazones of ketones with phenoxyacetyl chloride/Et3N in dichloromethane. This Thermo Scientific Chemicals brand product was originally part of the Alfa Aesar product portfolio. Some documentation and label information may refer to the legacy brand. The original Alfa Aesar product / item code or SKU reference has not changed as a part of the brand transition to Thermo Scientific Chemicals.

Notice:
Our products are intended for lab use only. For any other use, please contact us.
Brand:
Alfa Aesar By Thermo Fisher Scientific
Long term storage:
Notes:

Chemical properties

Molecular weight:
170.59
Formula:
C8H7ClO2
Purity:
98%
Color/Form:
Liquid, Clear colorless to yellow to brown
InChI:
InChI=1S/C8H7ClO2/c9-8(10)6-11-7-4-2-1-3-5-7/h1-5H,6H2
InChI key:
PKUPAJQAJXVUEK-UHFFFAOYSA-N
SMILES:
O=C(Cl)COc1ccccc1
MDL:
Melting point:
Boiling point:
Flash point:
Density:
Concentration:
EINECS:
Merck:
HS code:

Hazard Info

UN Number:
EQ:
Class:
H Statements:
P Statements:
Forbidden to fly:
Hazard Info:
Packing Group:
LQ:

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