1-Methoxy-3-trimethylsiloxy-1,3-butadiene, 96%

CAS: 54125-02-9

Ref. 02-L14672

Product Information

• Name: 1-Methoxy-3-trimethylsiloxy-1,3-butadiene, 96%
• Synonyms: danishefsky's diene, (E)-((3-Methoxy-1-(methylene)allyl)oxy)trimethylsilane, (E)-(3-Methoxy-1-methylene-2-propenyloxy)trimethylsilane, (E)-(4-Methoxybuta-1,3-dien-2-yloxy)trimethylsilane, (E)-1-Methoxy-3-(trimethylsilyloxy)-1,3-butadiene, (E)-1-Methoxy-3-trimethylsiloxy-1,3-butadiene, 1-Methoxy-3-(trimethylsilyloxy)-1,3-butadiene, 1-Methoxy-3-trimethylsiloxy-1,3-butadiene, Danishefsky-Kitahara diene, E-1-Methoxy-3-[(trimethylsilyl)oxy]buta-1,3-diene, Methyl 3-Trimethylsilyloxybuta-1,3-Dien-1-Yl Ether, Silane, [(3-methoxy-1-methylene-2-propenyl)oxy]trimethyl-, (E)-, Silane, [[(2E)-3-methoxy-1-methylene-2-propen-1-yl]oxy]trimethyl-, Silane, [[(2E)-3-methoxy-1-methylene-2-propenyl]oxy]trimethyl-, [((2E)-3-Methoxy-1-methyleneprop-2-en-1-yl)oxy]trimethylsilane, [(4-Methoxybuta-1,3-Dien-2-Yl)Oxy](Trimethyl)Silane, [[(2E)-3-Methoxy-1-methylene-2-propen-1-yl]oxy]trimethylsilane, [[(2E)-3-Methoxy-1-methylene-2-propenyl]oxy]trimethylsilane, [[(3E)-4-Methoxybuta-1,3-dien-2-yl]oxy](trimethyl)silane, trans-1-Methoxy-3-(trimethylsiloxy)-1,3-butadiene, trans-1-Methoxy-3-[(trimethylsilyl)oxy]-1,3-butadiene, {[(2E)-3-methoxy-1-methylideneprop-2-en-1-yl]oxy}(trimethyl)silane, {[(2Z)-3-methoxy-1-methylideneprop-2-en-1-yl]oxy}(trimethyl)silane

Description

1-Methoxy-3-trimethylsiloxy-1,3-butadiene is employed as a reagent in Mannich-Michael reaction for the synthesis of piperidinones and enaminones. As Diels-Alder diene, it is used in the synthesis of pyridones and pyranones, sulfone analogues of griseofulvin (sulfogriseofulvins) and 4H-1-aminopyrroles and 4, 5H-pyrazoles. This Thermo Scientific Chemicals brand product was originally part of the Alfa Aesar product portfolio. Some documentation and label information may refer to the legacy brand. The original Alfa Aesar product / item code or SKU reference has not changed as a part of the brand transition to Thermo Scientific Chemicals.

• Brand: Alfa Aesar By Thermo Fisher Scientific

Chemical properties

• Molecular weight: 172.30
• Formula: C₈H₁₆O₂Si
• Purity: 96%
• Color/Form: Clear colorless to yellow, Liquid
• InChI key: SHALBPKEGDBVKK-UHFFFAOYSA-N