6-Bromo-4-hydroxycoumarin
CAS: 4139-61-1
Ref. 3D-FB53836
| 1g | Discontinued | ||
| 2g | Discontinued | ||
| 5g | Discontinued | ||
| 10g | Discontinued | ||
| 25g | Discontinued |
Product Information
Name:
6-Bromo-4-hydroxycoumarin
Synonyms:
- 6-Bromo-4-hydroxy-2H-chromen-2-one
- 2H-1-Benzopyran-2-one, 6-bromo-4-hydroxy-
- 6-Bromo-4-hydroxy-2H-chromen-2-one
Description:
6-Bromo-4-hydroxycoumarin, also known as BrHCC, is an organic compound that belongs to the tetronic acid family. It was first synthesized in 1891 by the reaction of ethyl nitroacetate and homophthalic acid. 6-Bromo-4-hydroxycoumarin is a valued reagent for the synthesis of 1,3-dicarbonyl compounds due to its high yields, easy workup, and stereoselectivity. The synthesis of 6-bromo-4-hydroxycoumarin begins with the condensation of ethyl nitroacetate with pyridine in presence of hydrochloric acid to produce a mixture of methylene chloride and 4-hydroxycoumarin. This mixture is then heated at reflux for 24 hours. The final product is purified by fractional distillation.
Notice:
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Brand:
Biosynth
Long term storage:
Notes:
Chemical properties
Molecular weight:
241.04 g/mol
Formula:
C9H5BrO3
Purity:
Min. 95%
InChI:
InChI=1S/C9H5BrO3/c10-5-1-2-8-6(3-5)7(11)4-9(12)13-8/h1-4,11H
InChI key:
InChIKey=KNMCTCABMSGXGR-UHFFFAOYSA-N
SMILES:
O=c1cc(O)c2cc(Br)ccc2o1
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