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Di(o-tolyl)chlorophosphine
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Di(o-tolyl)chlorophosphine

CAS: 36042-94-1

Ref. 3D-FD149765

1g
310.00 €
2g
436.00 €
5g
647.00 €
10g
1,047.00 €
500mg
194.00 €
Estimated delivery in United States, on Tuesday 14 Jan 2025

Product Information

Name:
Di(o-tolyl)chlorophosphine
Synonyms:
  • Bis(2-Methylphenyl)Phosphinous Chloride
Description:

Di(o-tolyl)chlorophosphine is a chiral, asymmetric catalyst that has been used to synthesize tetrahydrofurans. This compound is prepared by a multimerization reaction of lithium metal and an o-tolylphosphine ligand in the presence of an injecting cocatalyst. This reaction is conducted in tetrahydrofuran at room temperature and requires a flow rate of 1.0 mL per minute. The use of this catalyst can be seen as a transition from the older, less efficient method of using phosphines as ligands for the synthesis of tetrahydrofurans with lithium aluminum hydride.

Notice:
Our products are intended for lab use only. For any other use, please contact us.
Brand:
Biosynth
Long term storage:
Notes:

Chemical properties

Molecular weight:
248.69 g/mol
Formula:
C14H14ClP
Purity:
Min. 95%
InChI:
InChI=1S/C14H14ClP/c1-11-7-3-5-9-13(11)16(15)14-10-6-4-8-12(14)2/h3-10H,1-2H3
InChI key:
InChIKey=KAAGXBGJRWFWPT-UHFFFAOYSA-N
SMILES:
Cc1ccccc1P(Cl)c1ccccc1C
MDL:
Melting point:
Boiling point:
Flash point:
Density:
Concentration:
EINECS:
Merck:
HS code:

Hazard Info

UN Number:
EQ:
Class:
H Statements:
P Statements:
Forbidden to fly:
Hazard Info:
Packing Group:
LQ:

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