(R)-1-[(S)-2-(Diphenylphosphino)ferrocenyl]ethyldi-tert-butylphosphine
CAS: 155830-69-6
Ref. 3D-FD179855
1g | 294.00 € | ||
2g | 465.00 € | ||
250mg | 136.00 € | ||
500mg | 193.00 € |
Product Information
- (R)1[(1S)2(diphenylphosphino)ferrocenyl] et-di-T-butylphosph
- (R)-(-)-1-[(S)-2-Diphenylphosphino)ferrocenyl]ethyldi-tert-butylphosphine
- (R)-1-[(1S)-2-(Diphenylphosphino)ferrocenyl]ethyldi-tert-butylphosphine
- Josiphos SLJ002-1
- 1,2,3,4,5-cyclopentanepentayl, compd. with 1-[(1R)-1-[bis(1,1-dimethylethyl)phosphino]ethyl]-2-(diphenylphosphino)-1,2,3,4,5-cyclopentanepentayl, iron salt (1:1:1)
- (R)-1-[(S)-2-(Dipheny1phosphino)ferroceny1] ethyldi-tert-butylphosphine
- (R)-(-)-1-[(S)-2-(Diphenylphosphino)ferrocenyl]ethyldi-t-butylphosphine
A novel, practical and efficient method for the preparation of (R)-1-[(S)-2-(diphenylphosphino)ferrocenyl]ethyldi-tert-butylphosphine is described. The asymmetric synthesis of ketones with high enantiomeric excess was achieved using this ligand in a one-pot, two-step procedure. The homogeneous catalytic reduction of nitriles to primary amines was also demonstrated. This methodology is applicable to the preparation of other chiral phosphines and phosphine derivatives.
Chemical properties
Technical inquiry about: 3D-FD179855 (R)-1-[(S)-2-(Diphenylphosphino)ferrocenyl]ethyldi-tert-butylphosphine
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