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3-Trifluoromethylbenzyl bromide
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3-Trifluoromethylbenzyl bromide

CAS: 402-23-3

Ref. 3D-FT11076

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Estimated delivery in United States, on Friday 17 Jan 2025

Product Information

Name:
3-Trifluoromethylbenzyl bromide
Synonyms:
  • 1-(Brommethyl)-3-(trifluormethyl)benzol
  • 3-(Bromomethyl)-1-(trifluoromethyl)benzene
  • 3-(Bromomethyl)benzotrifluoride
  • 3-(Trifluoromethyl)benzyl Bromide
  • 3-Trifluoromethylbenzylbromide
  • 402-23-3
  • Benzene, 1-(bromomethyl)-3-(trifluoromethyl)-
  • Fxffr C1E
  • m-(Trifluoromethyl)benzyl bromide
  • m-Trifluoromethylbenzyl bromide
  • See more synonyms
  • m-Xylene, α′-bromo-α,α,α-trifluoro-
  • α′-Bromo-α,α,α-trifluoro-m-xylene
  • 1-(Bromomethyl)-3-(trifluoromethyl)benzene
  • 1-Bromomethyl-3-Trifluoromethyl-Benzene
  • 1-(Bromomethyl)-3-(trifluoromethyl)benzene
Description:

3-Trifluoromethylbenzyl bromide is a chiral electrophile used in asymmetric synthesis. It can be prepared by the reaction of 3-bromobenzyl alcohol with trifluoromethylmagnesium chloride, followed by hydrolysis of the resulting benzylic alcohols. The compound has been shown to react with amides and diarylmethanes to produce pyrazoles and diarylmethanes, respectively. This reaction was optimized using a variety of techniques, including voltammetry and x-ray crystallographic studies. 3-Trifluoromethylbenzyl bromide has also been shown to be effective in the transfer hydrogenation of ketones to produce alcohols.

Notice:
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Brand:
Biosynth
Long term storage:
Notes:

Chemical properties

Molecular weight:
239.03 g/mol
Formula:
C8H6BrF3
Purity:
Min. 95%
InChI:
InChI=1S/C8H6BrF3/c9-5-6-2-1-3-7(4-6)8(10,11)12/h1-4H,5H2
InChI key:
InChIKey=MYYYZNVAUZVXBO-UHFFFAOYSA-N
SMILES:
FC(F)(F)c1cccc(CBr)c1
MDL:
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EINECS:
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Hazard Info

UN Number:
EQ:
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Forbidden to fly:
Hazard Info:
Packing Group:
LQ:

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