Product Information
- P,P-Bis(tricyclo[3.3.1.13,7]dec-1-yl)phosphinous chloride
- Diadamantylchlorophosphine
- Bis(1-adamantyl)phosphinous chloride
- Phosphinous chloride, P,P-bis(tricyclo[3.3.1.13,7]dec-1-yl)-
- Phosphinous chloride, bis(tricyclo[3.3.1.13,7]dec-1-yl)-
Di(1-adamantyl)chlorophosphine is a bifunctional ligand that can be used for the palladium-catalyzed coupling of aryl chlorides and amines. Di(1-adamantyl)chlorophosphine is synthesized from adamantane, phosphorous pentachloride, and anhydrous ammonia in the presence of catalytic amounts of palladium. Di(1-adamantyl)chlorophosphine is immobilized on silica gel to prevent hydrolysis. This ligand reacts with primary amines to form iminophosphoranes, which can then be reacted with aryl chlorides to form aryl chloroamines.
Chemical properties
Technical inquiry about: 3D-HGA28219 Di(1-adamantyl)chlorophosphine
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