3,4,6-Tri-O-acetyl-D-glucal

CAS: 2873-29-2

Ref. 3D-MT00681

Product Information

• Name: 3,4,6-Tri-O-acetyl-D-glucal
• Synonyms: 1,5-Anhydro-2-deoxy-D-arabino-hex-1-enitol triacetate, 1,2-Dideoxy-3,4,6-Tri-O-Acetyl-D-Arabino-1-Hexenopyranoside, 1,2-Dideoxy-3,4,6-tri-O-acetyl-D-arabino-1-hexenopyranose, 1,3,4-tri-O-acetyl-2,6-anhydro-5-deoxyhex-5-enitol, 1,5-Anhydro-2-deoxy-D-arabino-1-hexenol triacetate, 1,5-Anhydro-2-deoxy-D-arabino-hex-1-enitol 3,4,6-Tri-O-acetyl Ether, 1,5-Anhydro-2-desoxy-D-arabino-hex-1-enitoltriacetat, 3,4,6-Tri-O-Acetyl-1,5-Anhydro-D-Arabino-Hex-1-Enitol, 3,4,6-Tri-O-acetyl-1,2-dideoxy-<span class="text-smallcaps">D</span>-arabino-hex-1-enopyranose, 3,4,6-Tri-O-acetyl-1,2-dideoxy-D-arabino-hex-1-enopyranose, 3,4,6-Tri-O-acetyl-1,5-anhydro-2-deoxy-D-arabino-hex-1-enitol, 3,4,6-Tri-O-acetyl-<span class="text-smallcaps">D</span>-glucal, 3,4,6-Tri-O-acetylglucal, 3,4,6-Triacetylglucal, 3,4,6-Tris-O-acetyl-<span class="text-smallcaps">D</span>-glucal, 3,4,6-Tris-O-acetyl-D-glucal, <span class="text-smallcaps">D</span>-Glucal triacetate, <span class="text-smallcaps">D</span>-arabino-Hex-1-enitol, 1,5-anhydro-2-deoxy-, 3,4,6-triacetate, <span class="text-smallcaps">D</span>-arabino-Hex-1-enitol, 1,5-anhydro-2-deoxy-, triacetate, <span class="text-smallcaps">D</span>-arabino-Hex-1-enopyranose, 1,2-dideoxy-, triacetate, D-Glucal triacetate, D-Glucal-3,4,5-tri-O-acetate, D-arabino-Hex-1-enitol, 1,5-anhydro-2-deoxy-, 3,4,6-triacetate, D-arabino-Hex-1-enitol, 1,5-anhydro-2-deoxy-, triacetate, D-arabino-Hex-1-enopyranose, 1,2-dideoxy-, triacetate, Glucal (D)- Tri-O-Acetyl-, (-)-, Tri-O-acetyl-<span class="text-smallcaps">D</span>-glucal, Tri-O-acetylglucal, Triacetate de 1,5-anhydro-2-desoxy-D-arabino-hex-1-enitol, Triacetyl-<span class="text-smallcaps">D</span>-glucal, Triacetyl-D-glucal, triacetato de 1,5-anhidro-2-desoxi-D-arabino-hex-1-enitol

Description

3,4,6-Tri-O-acetyl-D-glucal, also called 1,5-anhydro-2-deoxy-D-arabino-hex-1-enitol triacetate, is the acetate protected cyclic enol-ether (glycal) of D-glucose. 3,4,6-Tri-O-acetyl-D-glucal is a building block useful in the synthesis of a range of carbohydrates with the glucal double bond allowing other functional groups to be introduced. As an alkene, a glycal can undergo electrophilic addition across the double bond to introduce halogens and epoxides or be used to generate deoxy monosaccharides. 3,4,6-Tri-O-acetyl-D-glucal can undergo a Ferrier rearrangement with an alcohol and Lewis acid to give a 2,3-unsaturated product.

• Brand: Biosynth

Chemical properties

• Molecular weight: 272.25 g/mol
• Formula: C₁₂H₁₆O₇
• Purity: Min. 98 Area-%
• Color/Form: White Off-White Powder