
1-TRIMETHYLSILYLPROPYNE
CAS:
Ref. 3H-SIT8606.5

Product Information
Name:1-TRIMETHYLSILYLPROPYNE
Brand:Gelest
Description:Alkynylsilane Cross-Coupling AgentThe cross-coupling reaction is a highly useful methodology for the formation of carbon-carbon bonds. It involves two reagents, with one typically being a suitable organometallic reagent - the nucleophile - and the other a suitable organic substrate, normally an unsaturated halide, tosylate or similar - the electrophile.1-Trimethylsilylpropyne; Propynyltrimethylsilane; 1-(Trimethylsilyl)prop-1-yneForms polymers with very high oxygen permeabilityUseful in Sonogashira reactionsPolymerization catalyzed with TaCl5/(C6H5)3BiConverts aldehydes to 1,3-dienes in presence of Cp2Zr(H)ClUsed in the preparation of alkynylxenon fluoridePolymeric version available, SSP-070Extensive review of silicon based cross-coupling agents: Denmark, S. E. et al. "Organic Reactions, Volume 75" Denmark, S. E. ed., John Wiley and Sons, 233, 2011
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Chemical properties
Molecular weight:112.25
Formula:C6H12Si
Purity:97%
Color/Form:Straw Liquid