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TRIMETHYLSILYL TRIFLUOROMETHANESULFONATE
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TRIMETHYLSILYL TRIFLUOROMETHANESULFONATE

CAS: 27607-77-8

Ref. 3H-SIT8620.0

25gTo inquire
20kgTo inquire
2.5kgTo inquire
225kgTo inquire
Estimated delivery in United States, on Tuesday 21 Jan 2025

Product Information

Name:
TRIMETHYLSILYL TRIFLUOROMETHANESULFONATE
Synonyms:
  • TRIMETHYLSILYLTRIFLATE
  • Methanesulfonate, Trimethylsilyl Trifluoro-
  • Methanesulfonic acid, 1,1,1-trifluoro-, trimethylsilyl ester
  • Silanol, trimethyl-, trifluoromethanesulfonate
  • TMSOTf
  • Trifluorometanosulfonato De Trimetilsililo
  • Trifluoromethanesulfonate de trimethylsilyle
  • Trifluoromethanesulfonic acid trimethylsilyl ester
  • Trimethylsilanol trifluoromethanesulfonate
  • Trimethylsilyl Trifluoromethanesulphonate
  • See more synonyms
  • Trimethylsilyl trfluoromethanesulfonate
  • Trimethylsilyl triflate
  • Trimethylsilyl trifluoromethanesulfonate
  • Trimethylsilyl trifluoromethylsulfonate
  • Trimethylsilyltrifluormethansulfonat
Description:

Trimethylsilyl Blocking Agent
Used as a protecting group for reactive hydrogens in alcohols, amines, thiols, and carboxylic acids. Organosilanes are hydrogen-like, can be introduced in high yield, and can be removed under selective conditions. They are stable over a wide range of reaction conditions and can be removed in the presence of other functional groups, including other protecting groups. The tolerance of silylated alcohols to chemical transformations summary is presented in Table 1 of the Silicon-Based Blocking Agents brochure.
Trimethylsilyltrifluoromethanesulfonate; Trimethylsilyltriflate; TMSOTf
Strong silylating agent for C- or O-silylationsReacts with nitroalkanes to give N,N-bis(trimethylsiloxy)enaminesNafion SAC-13 has been shown to be a recyclable catalyst for the trimethylsilylation of primary, secondary, and tertiary alcohols in excellent yields and short reaction timesSummary of selective deprotection conditions is provided in Table 7 through Table 20 of the Silicon-Based Blocking Agents brochure

Notice:
Our products are intended for lab use only. For any other use, please contact us.
Brand:
Gelest
Long term storage:
Notes:

Chemical properties

Molecular weight:
222.25
Formula:
C4H9F3O3SSi
Color/Form:
Straw Liquid
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Hazard Info

UN Number:
EQ:
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Forbidden to fly:
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Packing Group:
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