VINYLMETHYLDICHLOROSILANE

CAS: 124-70-9

Ref. 3H-SIV9084.0

Product Information

• Name: VINYLMETHYLDICHLOROSILANE
• Synonyms: (Dichloromethyl)(Ethenyl)Silane, Dichloro(Ethenyl)Methylsilane, Dichloroethenylmethylsilane, Dichlorovinylmethylsilane, Ls 190, MVS (silane), Methyldichlorovinylsilane, Methylethenyldichlorosilane, Methylvinyldichlorosilane, NSC 96610, Silane, dichloroethenylmethyl-, Silane, dichloromethylvinyl-, Vinylmethyldichlorosilane, Vinylmethyldichlorsilane
• CAS: 124-70-9

Description

Alkenylsilane Cross-Coupling Agent
The cross-coupling reaction is a highly useful methodology for the formation of carbon-carbon bonds. It involves two reagents, with one typically being a suitable organometallic reagent - the nucleophile - and the other a suitable organic substrate, normally an unsaturated halide, tosylate or similar - the electrophile.
Vinylmethyldichlorosilane; Dichlorovinylmethylsilane; Methylvinyldichlorosilane; Dichloroethenylmethylsilane
Viscosity: 0.70 cStΔHvap: 33.9 kJ/molCritical temperature: 272 °CCoefficient of thermal expansion: 1.4 x 10-3Reacts to vinylate aryl halides under NaOH-moderated conditionsUsed as a tether in synthesis of C-glycosidesExtensive review of silicon based cross-coupling agents: Denmark, S. E. et al. "Organic Reactions, Volume 75" Denmark, S. E. ed., John Wiley and Sons, 233, 2011

• Brand: Gelest

Chemical properties

• Molecular weight: 141.07
• Formula: C₃H₆Cl₂Si
• Purity: 97%
• Color/Form: Straw Amber Liquid