(Acetato-KappaO)[[2,2'-[(1R,2R)-1,2-cyclohexanediylbis[(nitrilo-KappaN)methylidyne]]bis[4,6-bis(1,1-dimethylethyl)phenolato-KappaO]](2-)]cobalt

CAS: 201870-82-8

Ref. TR-A161420

Product Information

• Name: (Acetato-KappaO)[[2,2'-[(1R,2R)-1,2-cyclohexanediylbis[(nitrilo-KappaN)methylidyne]]bis[4,6-bis(1,1-dimethylethyl)phenolato-KappaO]](2-)]cobalt
• Synonyms: (Acetato-kO)[[2,2'-[1,2-cyclohexanediylbis[(nitrilo-kN)methylidyne]]bis[4,6-bis(1,1-dimethylethyl)phenolato-kO]](2-)]-, [SP-5-13-(1R-trans)]-cobalt
• Brand: TRC
• Description: Applications A cobalt complex used as a chiral selector of PVC membrane electrode. A highly active catalysts for the copolymerization of propylene oxide and carbon dioxide. (R,R)-(-)-N,N′-Bis(3,5-di-tert-butylsalicylidene)-1,2-cyclohexanediamine (B431500) derivative, a ligand used in the preparation of Jacobsen's catalyst.References Cohen, C. et al.: J. Am. Chem. Soc., 127, 10869 (2005); Jacobsen, E.N. et al.: J. Am. Chem. Soc., 113, 7063 (1991)

Chemical properties

• Molecular weight: 662.79
• Formula: C₃₈H₅₅CoN₂O₄
• Color/Form: Neat
• InChI: InChI=1S/C36H54N2O2.C2H4O2.Co/c1-33(2,3)25-17-23(31(39)27(19-25)35(7,8)9)21-37-29-15-13-14-16-30(29)38-22-24-18-26(34(4,5)6)20-28(32(24)40)36(10,11)12;1-2(3)4;/h17-22,29-30,39-40H,13-16H2,1-12H3;1H3,(H,3,4);/q;;+3/p-3/t29-,30-;;/m1../s1
• InChI key: InChIKey=SZLTZRSRNDSBPH-SEILFYAJSA-K