(Acetonitrile)[4-tert-butyl-2-(diisopropylphosphino)-1-methyl-1H-imidazole-κN,κP](η5-cyclopentadienyl)ruthenium(1+) hexafluorophosphate
CAS:
Ref. TR-A164155
1mg
89.00€
5mg
98.00€
10mg
115.00€
Product Information
Name:(Acetonitrile)[4-tert-butyl-2-(diisopropylphosphino)-1-methyl-1H-imidazole-κN,κP](η5-cyclopentadienyl)ruthenium(1+) hexafluorophosphate
Controlled Product
Synonyms:
- (Acetonitrile)[4-tert-butyl-2-(diisopropylphosphino)-1-methyl-1H-imidazole-?N,?P](?5-cyclopentadienyl)ruthenium(1+) hexafluorophosphate
- (Acetonitrile)[4-tert-butyl-2-(diisopropylphosphino)-1-methyl-1H-imidazole-?N,?P](?5-cyclopentadienyl)ruthenium(1+) hexafluorophosphate
Brand:TRC
Description:Applications (Acetonitrile)[4-tert-butyl-2-(diisopropylphosphino)-1-methyl-1H-imidazole-κN,κP](η5-cyclopentadienyl)ruthenium(1+) hexafluorophosphate, is an Alkene Zipper Catalyst, used in selective transformation of a large variety of ω-alkenyl cyclopropylcarbinols into stereodefined unconjugated (E)-acyclic aldehydes .References Bruffaerts, J., Vasseur, A., & Marek, I. (2018). Alkene-Zipper Catalyzed Selective and Remote Retro-ene Reaction of Alkenyl Cyclopropylcarbinol. Advanced Synthesis & Catalysis, 360(7), 1389–1396.
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Chemical properties
Molecular weight:606.53
Formula:C21H35N3PRu·PF6
Color/Form:Off-White
InChI:InChI=1S/C15H27NP.C5H10.C2H5N.F5P.FH.Ru/c1-11(2)17(12(3)4)14-9-13(10-16(14)8)15(5,6)7;1-2-4-5-3-1;1-2-3;1-6(2,3,4)5;;/h10-12H,1-8H3;1-5H2;2-3H,1H3;;1H;
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