Product Information
Name:AD-mix-β (Technical Grade)
Controlled Product
Synonyms:
- AD-mix-beta
Brand:TRC
Description:Applications AD-mix-β is a catalyst employed in the Sharpless Asymmetric Dihyroxylation of (E,E)- or (E,Z)-1,3-dienoates. It is also used in the preparation of ß-hydroxy-γ-lactones from ß,γ-unsaturated esters.References Ahmed, M., et al.: J. Org. Chem., 71, 7741 (2006); Tretyakov, E., et al.: Eur. J. Org. Chem., 12, 2669 (2006)
Notice:Our products are intended for lab use only. For any other use, please contact us.
Chemical properties
Molecular weight:NA
Formula:C10H12NOBr
Color/Form:Neat
InChI:InChI=1S/C48H54N6O4/c1-5-29-27-53-21-17-31(29)23-43(53)45(35-15-19-49-41-13-11-33(55-3)25-39(35)41)57-47-37-9-7-8-10-38(37)48(52-51-47)58-46(44-24-32-18-22-54(44)28-30(32)6-2)36-16-20-50-42-14-12-34(56-4)26-40(36)42/h7-16,19-20,25-26,29-32,43-46H,5-6,17-18,21-24,27-28H2,1-4H3/t29-,30-,31-,32+,43+,44-,45+,46-/m0/s1
SMILES:CC[C@H]1CN2CC[C@H]1C[C@@H]2[C@H](Oc1nnc(O[C@@H](c2ccnc3ccc(OC)cc23)[C@@H]2C[C@H]3CCN2C[C@@H]3CC)c2ccccc12)c1ccnc2ccc(OC)cc12.N#C[Fe]([K])(C#N)(C#N)(C#N)(C#N)C#N.O=[C]OO[K].O=[Os](=O)(O)(O)(O)(O)([K])[K].[K].[K][K]
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