Bis(1,5-cyclooctadiene)diiridium(I) Dichloride

CAS: 12112-67-3

Ref. TR-B423265

Product Information

• Name: Bis(1,5-cyclooctadiene)diiridium(I) Dichloride
• Synonyms: Chloro(1,5-cyclooctadiene)iridium Dimer, Chloro(cyclooctadiene)iridium Dimer, Cyclooctadieneiridium Chloride Dimer, Di-µ-Chlorobis(1,5-cyclooctadiene)diiridium, Di-µ-Chlorobis(p-1,5-cyclooctadiene)diiridium, Di-µ-chlorobis(eta4-1,5-cyclooctadiene)diiridium, Di-µ-chlorobis(eta4-1,5-cyclooctadiene)diiridium(I), Di-µ-chlorobis[(1,2,5,6-eta)-1,5-cyclooctadiene]diiridium, Di-µ-chlorobis[(1,5-cyclooctadiene)iridium], Di-µ2-chlorobis(1,5-cyclooctadiene)diiridium, Dichlorobis(1,5-cyclooctadiene)diiridium, Dichlorobis(cyclooctadiene)diiridium, Dichlorobis(eta4-1,5-cyclooctadiene)diiridium, NSC 326162, µ,µ-Dichlorobis(1,5-cyclooctadiene)diiridium, Bis(µ-chloro)bis(1,5-cyclooctadiene)diiridium, Bis[µ-chloro(eta4-1,5-cyclooctadiene)iridium], Bis(chloro(1,5-cyclooctadiene)iridium), Bis(chloro(cyclooctadiene)iridium), Bis((µ-chloro)(1,5-cyclooctadiene)iridium), 5-Chlorobis(1,5-cyclooctadiene)diiridium, (eta4-1,5-Cyclooctadiene)iridium Chloride Dimer, (1,5-Cyclooctadiene)iridium Chloride Dimer, (1,5-Cyclooctadiene)chloroiridium Dimer, 1,5-Cyclooctadiene Iridium Complex, Bis(chloro(1,5-cyclooctadiene)iridium), (1,5-Cyclooctadiene)chloroiridium dimer, (1,5-Cyclooctadiene)iridium chloride dimer, (η4-1,5-Cyclooctadiene)iridium chloride dimer, (η⁴-1,5-Cyclooctadiene)iridium chloride dimer, 1,5-Cyclooctadiene, iridium complex, 1,5-cyclooctadiene, chloride, (1Z,5Z)-, diiridium salt, Bis((μ-chloro)(1,5-cyclooctadiene)iridium), Bis(1,5-cyclooctadiene)diiridium(I) dichloride, Bis(μ-chloro)bis(1,5-cyclooctadiene)diiridium, Bis[μ-chloro(η⁴-1,5-cyclooctadiene)iridium], Chloro(1,5-cyclooctadiene)iridium dimer, Chloro(cyclooctadiene)iridium dimer, Cyclooctadieneiridium chloride dimer, Di-Μ-Chlorobis[(1,2,5,6-Η)Cycloocta-1,5-Diene]Diiridium, Di-Μ-Clorobis[(1,2,5,6-Η)Cicloocta-1,5-Dien]Diiridio, Di-μ-Chlorobis(1,5-cyclooctadiene)diiridium, Di-μ-Chlorobis(π-1,5-cyclooctadiene)diiridium, Di-μ-chlorobis(η4-1,5-cyclooctadiene)diiridium, Di-μ-chlorobis(η4-1,5-cyclooctadiene)diiridium(I), Di-μ-chlorobis(η⁴-1,5-cyclooctadiene)diiridium, Di-μ-chlorobis(η⁴-1,5-cyclooctadiene)diiridium(I), Di-μ-chlorobis[(1,2,5,6-η)-1,5-cyclooctadiene]diiridium, Di-μ-chlorobis[(1,2,5,6-η)cycloocta-1,5-dien]diiridium, Di-μ-chlorobis[(1,5-cyclooctadiene)iridium], Di-μ2-chlorobis(1,5-cyclooctadiene)diiridium, Di-μ₂-chlorobis(1,5-cyclooctadiene)diiridium, Dichlorobis(η4-1,5-cyclooctadiene)diiridium, Dichlorobis(η⁴-1,5-cyclooctadiene)diiridium, Iridium, di-μ-chlorobis(1,5-cyclooctadiene)di-, Iridium, di-μ-chlorobis[(1,2,5,6-η)-1,5-cyclooctadiene]di-, Iridium, dichlorobis(cyclooctadiene)di-, Nsc 326162, μ,μ-Dichlorobis(1,5-cyclooctadiene)diiridium

Description

Applications Bis(1,5-cyclooctadiene)diiridium(I) Dichloride is a catalyst used in the iridium-catalyzed asymmetry hydrogenation of unfunctionalized exocyclic double carbon bonds. Also, it is used to test new NeoPHOX ligands derived from serine or threonine.
References Xia, J., et al.: Chem. Eur. J., 22, 18354-18357 (2016); Padevet, J., et al.: Beilstein J. Org. Chem., 12, 1185-1195 (2016)

• Brand: TRC

Chemical properties

• Molecular weight: 669.686
• Formula: C₁₆H₂₂Cl₂Ir₂
• Color/Form: Neat
• InChI: InChI=1S/2C8H10.2ClH.2Ir/c2*1-2-4-6-8-7-5-3-1;;;;/h2*1,8H,2,4-5,7H2;2*1H
• InChI key: InChIKey=VPJJNIRYZBAEAX-UHFFFAOYSA-N