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CAS 12112-67-3

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Di-μ-chlorobis[(1,2,5,6-η)-1,5-cyclooctadiene]diiridium

Description:
Di-μ-chlorobis[(1,2,5,6-η)-1,5-cyclooctadiene]diiridium, with the CAS number 12112-67-3, is a coordination compound featuring iridium as the central metal. This compound is characterized by its unique structure, which includes two iridium atoms bridged by two chloride ions (μ-chloride), and each iridium is further coordinated to a cyclooctadiene ligand. The cyclooctadiene ligands are known for their ability to form stable complexes with transition metals due to their π-acceptor properties. The compound exhibits interesting electronic and steric properties, making it relevant in various catalytic applications, particularly in organometallic chemistry. Its synthesis typically involves the reaction of iridium precursors with cyclooctadiene and chloride sources under controlled conditions. The presence of the bridging chlorides and the specific arrangement of the cyclooctadiene ligands contribute to the compound's reactivity and stability, which can be influenced by factors such as solvent and temperature. Overall, this compound serves as an important example of metal-ligand interactions in coordination chemistry.
Formula:C16H24Cl2Ir2
InChI:InChI=1S/2C8H12.2ClH.2Ir/c2*1-2-4-6-8-7-5-3-1;;;;/h2*1-2,7-8H,3-6H2;2*1H;;/q;;;;2*+1/p-2
InChI key:InChIKey=ZFOUDQNHNLDNLD-UHFFFAOYSA-L
SMILES:[Ir+]1234([Cl-][Ir+]567([Cl-]1)[CH]8=[CH]5CC[CH]6=[CH]7CC8)[CH]9=[CH]2CC[CH]3=[CH]4CC9
Synonyms:
  • (1,5-Cyclooctadiene)chloroiridium dimer
  • (1,5-Cyclooctadiene)iridium chloride dimer
  • (η4-1,5-Cyclooctadiene)iridium chloride dimer
  • (η<sup>4</sup>-1,5-Cyclooctadiene)iridium chloride dimer
  • 1,5-Cyclooctadiene, iridium complex
  • 1,5-cyclooctadiene, chloride, (1Z,5Z)-, diiridium salt
  • 5-Chlorobis(1,5-cyclooctadiene)diiridium
  • Bis((μ-chloro)(1,5-cyclooctadiene)iridium)
  • Bis(1,5-cyclooctadiene)diiridium(I) dichloride
  • Bis(chloro(1,5-cyclooctadiene)iridium)
  • See more synonyms
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