Bis(triphenylphosphoranylidene)ammonium Chloride

CAS: 21050-13-5

Ref. TR-B588710

Product Information

• Name: Bis(triphenylphosphoranylidene)ammonium Chloride
• Synonyms: Triphenyl(P,P,P-triphenylphosphine imidato)-phosphorus Chloride, (T-4)-Triphenyl(P,P,P-triphenylphosphine imidato-N)-phosphorus Chloride, P,P,P-triphenyl-Phosphine Imide Phosphorus Complex, 1,1,1,3,3,3-Hexaphenyl-3Lambda~5~-Diphosphaz-2-En-1-Ium Chloride, Bis(triphenylphosphine)iminium chloride~PPNCl, Bis(triphenylphosphine)iminium monochloride, Bis(triphenylphosphoranyldiene)ammonium chloride, Bis(triphenylphosphoranylidene)ammonium chloride, Bis(triphenylphosphoranylidene)iminium chloride, PPNCl, Phosphine imide, P,P,P-triphenyl-, phosphorus complex, Phosphorus(1+), triphenyl(P,P,P-triphenylphosphine imidato)-, chloride, Phosphorus(1+), triphenyl(P,P,P-triphenylphosphine imidato-N)-, chloride, (T-4)-, Phosphorus(1+), triphenyl(P,P,P-triphenylphosphine imidato-κN)-, chloride (1:1), (T-4)-, Phosphorus(1+), triphenyl(P,P,P-triphenylphosphine imidato-κN)-, chloride, (T-4)-, Triphenyl(P,P,P-triphenylphosphine imidato)phosphorus(1+) chloride, Triphenyl-Lambda~5~-Phosphaniminium Chloride (1:1)
• CAS: 21050-13-5

Description

Applications Bis(triphenylphosphoranylidene)ammonium chloride is a catalyst that is used in the preparation of 5-Hydroxy-clethodim Sulfoxide (H918380). 5-Hydroxy-clethodim Sulfoxide is an impurity of Clethodim (C573250), a post-emergent herbicide. Bis(triphenylphosphoranylidene)ammonium chloride is also a useful new reagent for the synthesis of nucleoside-5’-di and triphosphates.
References Falb, L.N., J. Agric. Food Chem., 38, 875 (1990); Hunter., J.H., et al.: Weed Technol., 9, 432 (1995); Beistein J. of Org. Chem. 11: 469 (2015)

• Brand: TRC

Chemical properties

• Molecular weight: 574.03
• Formula: C₃₆H₃₀ClNP₂
• Color/Form: Neat
• InChI: InChI=1S/C36H30NP2.ClH/c1-7-19-31(20-8-1)38(32-21-9-2-10-22-32,33-23-11-3-12-24-33)37-39(34-25-13-4-14-26-34,35-27-15-5-16-28-35)36-29-17-6-18-30-36;/h1-30H;1H/q+1;/p-1