[(η-6-Cymene)[(S,S)-1,2-diphenyl-N-tosyl-1,2-ethanediaminato]ruthenium] chloride]

CAS: 192139-90-5

Ref. TR-C989475

Product Information

• Name: [(η-6-Cymene)[(S,S)-1,2-diphenyl-N-tosyl-1,2-ethanediaminato]ruthenium] chloride]
• Synonyms: [RuCl(TsDPEN)(?-6-cymene)], [((S,S)-2-Amino-1,2-diphenylethyl)[(4-tolyl)sulfonyl]amido](chloro)(?6-p-cymene)ruthenium, [S-(R*,R*)]-[N-[2-(Amino-?N)-1,2-diphenylethyl]-4-methylbenzenesulfonamidato-?N]chloro[(1,2,3,4,5,6-?)-1-methyl-4-(1-methylethyl)benzene]ruthenium, [N-[(1S,2S)-2-(Amino-?N)-1,2-diphenylethyl]-4-methylbenzenesulfonamidato-?N]chloro[(1,2,3,4,5,6-?)-1-methyl-4-(1-methylethyl)benzene]ruthenium, (S,S)-N-(p-Toluenesulfonyl)-1,2-diphenylethanediamine(chloro)(p-cymene)ruthenium, [N-[(1S,2S)-2-(Amino-KN)-1,2-diphenylethyl]-4-methylbenzenesulfonamidato-KN]chloro[(1,2,3,4,5,6-η:)-1-methyl-4-(1-methylethyl)benzene]-ruthenium, RuCl(p-cymene)[(S,S)-Ts-DPEN], Chloro{[(1S,2S)-(+)-amino-1,2-diphenylethyl](4-toluenesulfonyl)amido}(p-cymene)ruthenium(II), Chloro{[(1S,2S)-(+)-2-amino-1,2-diphenylethyl](4-toluenesulfonyl)amido}(p-cymene)ruthenium(II)

Description

Applications [(η-6-Cymene)[(S,S)-1,2-diphenyl-N-tosyl-1,2-ethanediaminato]ruthenium] chloride] is an catalyst used for enantioselective hydrogenation of quinolines, N-Alky Ketimines and antitumor, antiproliferative derivatives of natural products isolated from bacteria.
References Bligh, C.M., et al.: J. Org. Chem., 79, 328 (2014); Brownell, K.R., et la.: J. Am. Chem. Soc., 135, 14299 (2013);

• Brand: TRC

Chemical properties

• Molecular weight: 636.21
• Formula: C₃₁H₃₅ClN₂O₂RuS
• Color/Form: Neat
• InChI: InChI=1S/C21H21N2O2S.C10H14.ClH.Ru/c1-16-12-14-19(15-13-16)26(24,25)23-21(18-10-6-3-7-11-18)20(22)17-8-4-2-5-9-17;1-8(2)10-6-4-9(3)5-7-10;;/h2-15,20-21H,22H2,1H3;4-8H,1-3H3;1H;/q-1;;;+2/p-1/t20-,21-;;;/m0.../s1
• InChI key: InChIKey=KJHYAEZMOHLVCH-UHFFFAOYSA-N
• SMILES: CCc1cc2ccccc2o1