CAS 192139-90-5

(S,S)-N-(p-Toluenesulfonyl)-1,2-diphenylethanediamine(chloro)(p-cymene)ruthenium(II)

Description:

(S,S)-N-(p-Toluenesulfonyl)-1,2-diphenylethanediamine(chloro)(p-cymene)ruthenium(II), with CAS number 192139-90-5, is a coordination complex of ruthenium that features a chiral diamine ligand. This compound is characterized by its ruthenium center coordinated to a p-cymene ligand and a chloro ligand, along with a sulfonamide moiety that imparts chirality. The presence of the p-toluenesulfonyl group enhances solubility and stability, making it suitable for various catalytic applications, particularly in asymmetric synthesis. The compound exhibits properties typical of transition metal complexes, including potential catalytic activity in organic transformations. Its chiral nature allows for the selective formation of enantiomers, which is valuable in the synthesis of pharmaceuticals and fine chemicals. Additionally, the stability of the ruthenium center under various reaction conditions contributes to its utility in catalysis. Overall, this compound represents a significant tool in the field of organometallic chemistry and catalysis, particularly in processes requiring chirality.

Formula: C₃₂H₄₄ClN₂O₂RuS

InChI: InChI=1/C21H21N2O2S.C10H20.CH3.ClH.Ru/c1-16-12-14-19(15-13-16)25(24)26-23-21(18-10-6-3-7-11-18)20(22)17-8-4-2-5-9-17;1-8(2)10-6-4-9(3)5-7-10;;;/h2-15,20-22,24H,1H3;8-10H,4-7H2,1-3H3;1H3;1H;/q-2;;;;+3/p-1/t20-,21-;9-,10+;;;/m0..../s1/rC22H24ClN2O2RuS.C10H20/c1-17-13-15-20(16-14-17)27(26)29-25-22(19-11-7-4-8-12-19)21(24-28(25,2)23)18-9-5-3-6-10-18;1-8(2)10-6-4-9(3)5-7-10/h3-16,21-22,24,26H,1-2H3;8-10H,4-7H2,1-3H3/t21-,22-;9-,10+/m0./s1

SMILES: Cc1ccc(cc1)[O+](O)S[N-]C(c1ccccc1)C(C1=C[CH][CH-]C=C1)[NH-].CC(C)C1CCC(C)CC1.C.Cl.[Ru]

Synonyms:

• (S,S)-N-(p-Toluenesulfonyl)-1,2-diphenylethanediamine(chloro)(p-cymene)ruthenium
• [N-[(1S,2S)-2-(Amino-KN)-1,2-diphenylethyl]-4-methylbenzenesulfonamidato-KN]chloro[(1,2,3,4,5,6-η:)-1-methyl-4-(1-methylethyl)benzene]-ruthenium
• RuCl(p-cymene)[(S,S)-Ts-DPEN]
• Chloro{[(1S,2S)-(+)-amino-1,2-diphenylethyl](4-toluenesulfonyl)amido}(p-cymene)ruthenium(II)
• Chloro{[(1S,2S)-(+)-2-amino-1,2-diphenylethyl](4-toluenesulfonyl)amido}(p-cymene)ruthenium(II)

RuCl[(S,S)-Tsdpen](p-cymene)

CAS: 192139-90-5

Formula: C₃₁H₃₅ClN₂O₂RuS

Purity: >90%(HPLC)

Color and Shape: Yellow to Amber to Dark red powder to crystal

Molecular weight: 636.21

Ref: 3B-R0124

Chloro{[(1S,2S)-(+)-2-amino-1,2-diphenylethyl](4-toluenesulfonyl)amido}(p-cymene)ruthenium(II), min. 90% RuCl[(S,S)-Tsdpen](p-cymene)

CAS: 192139-90-5

Chloro{[(1S,2S)-(+)-2-amino-1,2-diphenylethyl](4-toluenesulfonyl)amido}(p-cymene)ruthenium(II), min. 90% RuCl[(S,S)-Tsdpen](p-cymene)

Formula: C₃₁H₃₅ClN₂O₂RuS

Purity: min. 90%

Color and Shape: yellow to dark brown solid

Molecular weight: 636.21

Ref: 08-44-0149

(S,S)-N-(p-Toluenesulfonyl)-1,2-diphenylethanediamine(chloro)(p-cymene)ruthenium(II)

CAS: 192139-90-5

Formula: C₃₁H₃₅ClN₂O₂RuS

Purity: 97%

Color and Shape: Solid

Molecular weight: 636.2098

Ref: IN-DA003A9P

(S,S)-N-(p-Toluenesulfonyl)-1,2-Diphenylethanediamine(Chloro)(p-Cymene)Ruthenium(II)

CAS: 192139-90-5

(S,S)-N-(p-Toluenesulfonyl)-1,2-Diphenylethanediamine(Chloro)(p-Cymene)Ruthenium(II)

Purity: 98%

Molecular weight: 636.21g/mol

Ref: 54-IN10303

(S,S)-N-(p-Toluenesulfonyl)-1,2-diphenyl ethanediamine(chloro)(p-cymene)ruthenium(II)

CAS: 192139-90-5

(S,S)-N-(p-Toluenesulfonyl)-1,2-diphenylethanediamine(chloro)(p-cymene)ruthenium(II) is an organic compound that belongs to the class of solvents. It is a reagent that is used in acidic conditions. The elimination of hydrocarbons from (S,S)-N-(p-toluenesulfonyl)-1,2-diphenylethanediamine(chloro)(p-cymene)ruthenium(II) is carried out by chloroform or hexane and potassium hydroxide. This compound can be purified by recrystallization from aqueous ethanol or preparative thin layer chromatography with chloroform as eluent. Recycling of this compound is possible.

Formula: C₃₁H₃₅ClN₂O₂RuS

Color and Shape: Powder

Molecular weight: 636.21 g/mol

Ref: 3D-FT142036

[(η-6-Cymene)[(S,S)-1,2-diphenyl-N-tosyl-1,2-ethanediaminato]ruthenium] chloride]

Controlled Product

CAS: 192139-90-5

Applications [(η-6-Cymene)[(S,S)-1,2-diphenyl-N-tosyl-1,2-ethanediaminato]ruthenium] chloride] is an catalyst used for enantioselective hydrogenation of quinolines, N-Alky Ketimines and antitumor, antiproliferative derivatives of natural products isolated from bacteria.
References Bligh, C.M., et al.: J. Org. Chem., 79, 328 (2014); Brownell, K.R., et la.: J. Am. Chem. Soc., 135, 14299 (2013);

Formula: C₃₁H₃₅ClN₂O₂RuS

Color and Shape: Neat

Molecular weight: 636.21

Ref: TR-C989475

(S,S)-Ts-DPEN

CAS: 192139-90-5

Purity: 98%

Color and Shape: Solid

Molecular weight: 636.21

Ref: 10-F987250