1,2:5,6-Di-O-isopropylidene-α-D-glucofuranose 3-p-Toluenesulfonate

CAS: 3253-75-6

Ref. TR-D458030

Product Information

• Name: 1,2:5,6-Di-O-isopropylidene-α-D-glucofuranose 3-p-Toluenesulfonate
• Synonyms: 1,2:5,6-Di-O-isopropylidene-glucofuranose p-Toluenesulfonate, 1,2:5,6-Bis-O-(1-methylethylidene)-α-D-glucofuranose 4-Methylbenzenesulfonate, Furo[2,3-d]-1,3-dioxole α-D-glucofuranose Deriv., NSC 14163
• Brand: TRC
• Description: Applications 1,2:5,6-Di-O-isopropylidene-α-D-glucofuranose 3-p-Toluenesulfonate is used in the synthesis of a highly constrained adenosine derivative of 5’-Deoxy-5’-methylthioadenosine (MTA) which is 4’,4’-spirothietane-2’,N3-cycloadenosine.References De Carvalho, G. S. G., et al.: Tetrahedron Lett., 50, 463-466 (2009)

Chemical properties

• Molecular weight: 414.47
• Formula: C₁₉H₂₆O₈S
• Color/Form: Neat
• InChI: InChI=1S/C19H26O8S/c1-11-6-8-12(9-7-11)28(20,21)27-15-14(13-10-22-18(2,3)24-13)23-17-16(15)25-19(4,5)26-17/h6-9,13-17H,10H2,1-5H3/t13-,14-,15+,16-,17-/m1/s1
• InChI key: InChIKey=FOVFLADZRUACHW-NQNKBUKLSA-N
• SMILES: Cc1ccc(S(=O)(=O)O[C@H]2[C@@H]([C@H]3COC(C)(C)O3)O[C@@H]3OC(C)(C)O[C@H]23)cc1