(4R,5R)-2,2-Dimethyl-α,α,α',α'-tetra-2-naphthalenyl-1,3-dioxolane-4,5-dimethanol
CAS:
Ref. TR-D479455
5g
1,530.00€
Product Information
Name:(4R,5R)-2,2-Dimethyl-α,α,α',α'-tetra-2-naphthalenyl-1,3-dioxolane-4,5-dimethanol
Controlled Product
Synonyms:
- (4R,5R)-2,2-Dimethyl-alpha,alpha,alpha',alpha'-tetra-2-naphthalenyl-1,3-dioxolane-4,5-dimethanol
- (4R,5R)-2,2-Dimethyl-α4,α4,α5,α5-tetra-2-naphthalenyl-1,3-dioxolane-4,5-dimethanol
- (4R-trans)-2,2-Dimethyl-α,α,α',α'-tetra-2-naphthalenyl-1,3-dioxolane-4,5-dimethanol
Brand:TRC
Description:Applications (4R,5R)-2,2-Dimethyl-α,α,α',α'-tetra-2-naphthalenyl-1,3-dioxolane-4,5-dimethanol, is a privileged ligand analogue of TADDOLs. It can be broadly used in asymmetric synthesis. It is also shown that the titanium TADDOLate catalysts have broad application towards carbonyl addition and cycloaddition.References Seebach, D., et al.: Ange. Chem. Inter. Ed., 40, 92, (20010;
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Chemical properties
Molecular weight:666.802
Formula:C47H38O4
Color/Form:Neat
InChI:InChI=1S/C47H38O4/c1-45(2)50-43(46(48,39-23-19-31-11-3-7-15-35(31)27-39)40-24-20-32-12-4-8-16-36(32)28-40)44(51-45)47(49,41-25-21-33-13-5-9-17-37(33)29-41)42-26-22-34-14-6-10-18-38(34)30-42/h3-30,43-44,48-49H,1-2H3/t43-,44-/m1/s1
InChI key:InChIKey=QWADMRIAKWGVBF-NDOUMJCMSA-N
SMILES:CC1(C)O[C@@H](C(O)(c2ccc3ccccc3c2)c2ccc3ccccc3c2)[C@H](C(O)(c2ccc3ccccc3c2)c2ccc3ccccc3c2)O1
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