![Methyl 2-[Bis(2,2,2-trifluoroethoxy)phosphinyl]propionate](/_next/image/?url=https%3A%2Fstatic.cymitquimica.com%2Fproducts%2FTR%2Fthumb-webp%2FM296315.webp&w=3840&q=75)
Product Information
Name:Methyl 2-[Bis(2,2,2-trifluoroethoxy)phosphinyl]propionate
Controlled Product
Synonyms:
- Methyl 2-[Bis-O-(2,2,2-trifluoroethyl)phosphono]propionate
- 2-[Bis(2,2,2-trifluoroethoxy)phosphinyl]-methyl Ester Propanoic Acid
Brand:TRC
Description:Applications Methyl 2-[Bis(2,2,2-trifluoroethoxy)phosphinyl]propionate is synthetic reagent used in Z-selective HWE reactions (a.k.a. Still-Genari modification) to make alpha,β-unsaturated esters. Methyl 2-[Bis(2,2,2-trifluoroethoxy)phosphinyl]propionate is used as reagent/reactant for preparation of (±)-(Z)-2β-hydroxy-14-hydro-β-santalol via tandem radical cyclization.References Ishigami, K., et al.: Tetrahedron Lett., 42, 5816-5819 (2015)
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Chemical properties
Molecular weight:332.13
Formula:C8H11F6O5P
Color/Form:Neat
InChI:InChI=1S/C8H11F6O5P/c1-5(6(15)17-2)20(16,18-3-7(9,10)11)19-4-8(12,13)14/h5H,3-4H2,1-2H3
InChI key:InChIKey=OSBYRKXGZBJVAQ-UHFFFAOYSA-N
SMILES:COC(=O)C(C)P(=O)(OCC(F)(F)F)OCC(F)(F)F
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