Rhodium Carbonyl Chloride

CAS: 14523-22-9

Ref. TR-R318845

Product Information

• Name: Rhodium Carbonyl Chloride
• Synonyms: carbon monoxide;rhodium(1+);dichloride, Bis(chlororhodiumdicarbonyl), Bis(dicarbonyl(μ-chloro)rhodium), Bis(dicarbonylchlororhodium), Bis(dicarbonylrhodium chloride), Bis(μ-chloro)bis(dicarbonylrhodium), Carbon Monoxide, Chlorodicarbonylrhodium dimer, Chlorodicarbonylrhodium(I) dimer, Chlororhodium dicarbonyl dimer, Di-Mu-Chloro-Bis(Dicarbonylrhodium), Di-My-Chloro-Tetracarbonyldirhodium, Di-mu-chloro-tetracarbonyldirhodium, Di-Μ-Chloro-Bis(Dicarbonylrhodium), Di-Μ-Cloro-Bis(Dicarbonilrodio), Di-μ-Chlorotetracarbonyldirhodium(I), Di-μ-chlor-bis(dicarbonylrhodium), Dicarbonylchlororhodium dimer, Dicarbonylrhodium chloride dimer, Dichloride, Dichlorodirhodiumtetracarbonyl, Dichlorotetracarbonyldirhodium, Dirhodium tetracarbonyl dichloride, Nsc 120116, Rhodium carbonyl chloride, Rhodium carbonyl chloride (Rh2(CO)4Cl2), Rhodium carbonyl chloride (Rh₂(CO)₄Cl₂), Rhodium carbonyl chloride dimer, Rhodium dicarbonyl chloride dimer, Rhodium(+1) Cation, Rhodium, tetracarbonyldi-μ-chlorodi-, Tetracarbonyl-μ,μ'-dichlorodirhodium, Tetracarbonyl-μ,μ'-dichlorodirhodium(I), Tetracarbonylbis(μ-chloro)dirhodium, Tetracarbonyldi-μ-chlorodirhodium, Tetracarbonyldichlorodirhodium, [Rh(CO)2Cl]2, tetracarbonyldi-U-chlorodirhodium(I), μ-Dichlorotetracarbonyldirhodium

Description

Applications Rhodium Carbonyl Chloride is a reagent for rhodium-catalyzed [4+2+1] cycloaddition of in situ generated ene/yne-ene-allenes and carbon monoxide to produce [4+2+1] cycloadducts
References Tian, Z.Y., et al.: Angewandte Chemie Int. Ed.’ 57, 15544 (2018)

• Brand: TRC

Chemical properties

• Molecular weight: 388.757
• Formula: COClRh
• Color/Form: Neat
• InChI: InChI=1S/4CO.2ClH.2Rh/c4*1-2;;;;/h;;;;2*1H;;/q;;;;;;2*+1/p-2