(R)-RuCl[(p-cymene)(BINAP)]Cl

CAS: 145926-28-9

Ref. TR-R701576

Product Information

• Name: (R)-RuCl[(p-cymene)(BINAP)]Cl
• Synonyms: Chloro[(R)-2,2'-bis(diphenylphosphino)-1,1'-binaphthyl](p-cymene)ruthenium(II) Chloride, Chloro[(S)-(-)-2,2'-Bis(diphenylphosphino)-1,1'-Binaphthyl](P-cymene)ruthenium (II) chloride, Chloro[(R)-(+)-2,2'-Bis(diphenylphosphino)-1,1'-Binaphthyl](P-cymene)ruthenium (II) chloride, (R)-(+)-2,2'-[Bis(diphenylphosphino)-1,1'-Binaphthyl]Chloro(P-cymene)ruthenium, [(R)-2,2'-Bis-(diphenylphosphino)-1,1'-Binaphthyl]-Chloro-(P-cymene)-rutheniumchloride, [(S)-2,2'-Bis-(diphenylphosphino)-1,1'-Binaphthyl]-Chloro-(P-cymene)-rutheniumchloride, (S)-(-)-2,2'-Bis(diphenylphosphino)-1,1'-binaphthaleneChloro(P-cymene)ruthenium chloride, S-(-)-BINAP-Chloro(P-cymene)ruthenium chloride, Dichlororuthenium, [1-(2-Diphenylphosphanyl-1-Naphthyl)-2-Naphthyl]-Diphenyl-Phosphane, 1-Isopropyl-4-Methyl-Benzene, [RuCl(p-cymene)((R)-binap)]Cl, [Ru(R-Binap)(p-cymene)Cl]Cl

Description

Applications (R)-RuCl[(p-cymene)(BINAP)]Cl is a ruthenium BINAP catalysts.
References Yue, C., et al.: Yingyong Huagong, 43, 1042 (2014); Bernas, H., et al.: Catal. Sci. Technol., 2, 1901 (2012)

• Brand: TRC

Chemical properties

• Molecular weight: 943.901
• Formula: C₄₅H₃₅ClP₂Ru·C₁₀H₁₄·Cl
• Color/Form: Off-White
• InChI: InChI=1S/C44H32P2.C10H14.CH3.2ClH.Ru/c1-5-19-35(20-6-1)45(36-21-7-2-8-22-36)41-31-29-33-17-13-15-27-39(33)43(41)44-40-28-16-14-18-34(40)30-32-42(44)46(37-23-9-3-10-24-37)38-25-11-4-12-26-38;1-8(2)10-6-4-9(3)5-7-10;;;;/h1-32H;4-8H,1-3H3;1H3;2*1H;/q;;;;;+2/p-2
• SMILES: C[Ru+]1(Cl)[P](c2ccccc2)(c2ccccc2)c2ccc3ccccc3c2-c2c(ccc3ccccc23)[P]1(c1ccccc1)c1ccccc1.Cc1ccc(C(C)C)cc1.[Cl-]