Product Information
Name:Trimethylsilylethynyl(phenyl)iodonium Tetrafluoroborate
Controlled Product
Synonyms:
- Phenyl[2-(trimethylsilyl)ethynyl]Iodonium Tetrafluoroborate
Brand:TRC
Description:Applications Trimethylsilylethynyl(phenyl)iodonium Tetrafluoroborate is used in synthesis of 1-Alkynyl(triphenyl)arsonium Tetrafluoroborates by onium transfer reaction of 1-Alkynyl(phenyl)iodonium Tetrafluoroborates with Triphenylarsine. Also, used in preparation of Furan- and Thiophene-substituted alkynes and alkynyl ketones by Copper Iodide-catalyzed coupling and carbonylation of Heterocyclic Boronic Acids with Alkynyliodonium salts.References Nagaoka, T., et al.: Tetrah. Lett., 36, 261-4 (1995); Yu, Chan-Mo, et al.: Synlett, 2631-2634 (2005);
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Chemical properties
Molecular weight:301.22 + 86.81
Formula:C11H14ISi•BF4
Color/Form:Neat
InChI:InChI=1S/C11H14ISi.BF4/c1-13(2,3)10-9-12-11-7-5-4-6-8-11;2-1(3,4)5/h4-8H,1-3H3;/q+1;-1
InChI key:InChIKey=CZDYPVPMEAXLPK-UHFFFAOYSA-N
SMILES:C[Si](C)(C)C#C[I+]c1ccccc1.F[B-](F)(F)F
Technical inquiry about: Trimethylsilylethynyl(phenyl)iodonium Tetrafluoroborate
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