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CAS 12092-47-6

:

Di-μ-chlorobis[(1,2,5,6-η)-1,5-cyclooctadiene]dirhodium

Description:
Di-μ-chlorobis[(1,2,5,6-η)-1,5-cyclooctadiene]dirhodium, with the CAS number 12092-47-6, is a coordination compound featuring rhodium as the central metal. This compound is characterized by its unique structure, which includes two rhodium atoms bridged by two chloride ions (μ-chloro) and coordinated to two cyclooctadiene ligands. The cyclooctadiene ligands are arranged in a way that allows for η^1 and η^5 coordination modes, contributing to the compound's stability and reactivity. Di-μ-chlorobis[(1,2,5,6-η)-1,5-cyclooctadiene]dirhodium is notable for its applications in catalysis, particularly in organic synthesis, where it can facilitate various reactions due to the presence of the rhodium metal center. The compound exhibits interesting electronic properties and can participate in redox reactions, making it a subject of study in coordination chemistry and catalysis. Its synthesis typically involves the reaction of rhodium precursors with cyclooctadiene and chloride sources under controlled conditions.
Formula:C16H24Cl2Rh2
InChI:InChI=1S/2C8H12.2ClH.2Rh/c2*1-2-4-6-8-7-5-3-1;;;;/h2*1-2,7-8H,3-6H2;2*1H;;/q;;;;2*+1/p-2
InChI key:InChIKey=QSUDXYGZLAJAQU-UHFFFAOYSA-L
SMILES:[Rh+]1234([Cl-][Rh+]567([Cl-]1)[CH]8=[CH]5CC[CH]6=[CH]7CC8)[CH]9=[CH]2CC[CH]3=[CH]4CC9
Synonyms:
  • (1,5-Cyclooctadiene)rhodium chloride dimer
  • (1,5-Cyclooctadiene)rhodium(I) chloride dimer
  • (1Z,5Z)-cycloocta-1,5-diene
  • (η4-1,5-Cyclooctadiene)rhodium chloride dimer
  • (η<sup>4</sup>-1,5-Cyclooctadiene)rhodium chloride dimer
  • 1,5-Cyclooctadiene, rhodium complex
  • 1,5-cyclooctadiene, chloride, (1Z,5Z)-, dirhodium salt
  • Bis((1,5-cyclooctadiene)(chloro)rhodium)
  • Bis((μ-chloro)(η4-1,5-cyclooctadiene)rhodium)
  • Bis((μ-chloro)(η<sup>4</sup>-1,5-cyclooctadiene)rhodium)
  • See more synonyms
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Found 9 products.
  • Chloro(1,5-cyclooctadiene)rhodium(I) Dimer

    CAS:
    Formula:C16H24Cl2Rh2
    Purity:>98.0%(T)
    Color and Shape:Light yellow to Brown powder to crystal
    Molecular weight:493.08

    Ref: 3B-B1045

    1g
    462.00€
    100mg
    70.00€
  • Chloro(1,5-cyclooctadiene)rhodium(I) dimer

    CAS:
    <p>It is a widely used precursor to homogeneous catalysts. This is a chiral catalyst capable of asymmetrically hydrogenating certain prochiral alkenes. Chloro(1,5-cyclooctadiene)rhodium(I) dimer is also used in the synthesis of other metal ligands for use in catalysis. This Thermo Scientific Chemic</p>
    Formula:C16H24Cl2Rh2
    Molecular weight:493.08

    Ref: 02-010466

    1g
    To inquire
    250mg
    To inquire
  • Chloro(1,5-cyclooctadiene)rhodium(I) dimer, 98%

    CAS:
    <p>Chloro(1,5-cyclooctadiene)rhodium(I) dimer, 98%</p>
    Formula:RhClC8H12)
    Purity:98%
    Color and Shape:yellow to orange xtl.
    Molecular weight:493.08

    Ref: 08-45-0380

    1g
    1,249.00€
    5g
    4,985.00€
    250mg
    428.00€
  • Chloro(1,5-cyclooctadiene)rhodium(I) dimer

    CAS:
    Formula:C16H24Cl2Rh2
    Purity:98%
    Color and Shape:Solid
    Molecular weight:493.0788

    Ref: IN-DA0034L9

    1g
    293.00€
    5g
    To inquire
    100mg
    69.00€
    250mg
    130.00€
  • Ref: 7W-GX3020

    ne
    To inquire
  • Chloro(cycloocta-1,5-diene)rhodium(I) dimer

    CAS:
    <p>Chloro(cycloocta-1,5-diene)rhodium(I) dimer</p>
    Formula:ClRh·C8H12
    Purity:98%,Rh:41%,high pure
    Color and Shape: orange crystals
    Molecular weight:493.07876g/mol

    Ref: 54-OR70089

    1g
    504.00€
    5g
    1,614.00€
    100mg
    89.00€
    250mg
    147.00€
  • Chloro(1,5-cyclooctadiene)rhodium(I) Dimer

    Controlled Product
    CAS:
    Formula:C16H24Cl2Rh2
    Color and Shape:Neat
    Molecular weight:493.08

    Ref: TR-C293350

    2g
    939.00€
    5g
    1,257.00€
    500mg
    304.00€
  • Chloro(1,5-cyclooctadiene)rhodium(I) dimer

    CAS:
    <p>The rhodium(I) chloro(1,5-cyclooctadiene)dimer is an organometallic compound. It is a precursor to other organometallic compounds and has been used in hydrogenations and acetonitrile-tetrahydrofuran reactions. The synthesis of the chloro(1,5-cyclooctadiene)rhodium(I) dimer is based on the reaction of 1,5-cyclooctadiene with chloride followed by treatment with rhodium metal. The main use of this compound is as a precursor to other organometallics that are insoluble in organic solvents.</p>
    Formula:C16H24Cl2Rh2
    Purity:(Icp) Min. 98%
    Color and Shape:Powder
    Molecular weight:493.08 g/mol

    Ref: 3D-FC36866

    1g
    410.00€
    5g
    1,106.00€
    10g
    1,844.00€
    250mg
    189.00€
    500mg
    291.00€
  • Chloro(1,5-cyclooctadiene)rhodium(I)dimer

    CAS:
    Formula:C16H24Cl2Rh2
    Purity:95%
    Color and Shape:Solid, Crystalline
    Molecular weight:493.08

    Ref: 10-F048598

    1g
    325.00€
    2g
    585.00€
    5g
    1,310.00€
    100mg
    49.00€
    250mg
    95.00€