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CAS 12092-47-6

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Di-μ-chlorobis[(1,2,5,6-η)-1,5-cyclooctadiene]dirhodium

Description:
Di-μ-chlorobis[(1,2,5,6-η)-1,5-cyclooctadiene]dirhodium, with the CAS number 12092-47-6, is a coordination compound featuring rhodium as the central metal. This compound is characterized by its unique structure, which includes two rhodium atoms bridged by two chloride ions (μ-chloro) and coordinated to two cyclooctadiene ligands. The cyclooctadiene ligands are arranged in a way that allows for η^1 and η^5 coordination modes, contributing to the compound's stability and reactivity. Di-μ-chlorobis[(1,2,5,6-η)-1,5-cyclooctadiene]dirhodium is notable for its applications in catalysis, particularly in organic synthesis, where it can facilitate various reactions due to the presence of the rhodium metal center. The compound exhibits interesting electronic properties and can participate in redox reactions, making it a subject of study in coordination chemistry and catalysis. Its synthesis typically involves the reaction of rhodium precursors with cyclooctadiene and chloride sources under controlled conditions.
Formula:C16H24Cl2Rh2
InChI:InChI=1S/2C8H12.2ClH.2Rh/c2*1-2-4-6-8-7-5-3-1;;;;/h2*1-2,7-8H,3-6H2;2*1H;;/q;;;;2*+1/p-2
InChI key:InChIKey=QSUDXYGZLAJAQU-UHFFFAOYSA-L
SMILES:[Rh+]1234([Cl-][Rh+]567([Cl-]1)[CH]8=[CH]5CC[CH]6=[CH]7CC8)[CH]9=[CH]2CC[CH]3=[CH]4CC9
Synonyms:
  • (1,5-Cyclooctadiene)rhodium chloride dimer
  • (1,5-Cyclooctadiene)rhodium(I) chloride dimer
  • (1Z,5Z)-cycloocta-1,5-diene
  • (η4-1,5-Cyclooctadiene)rhodium chloride dimer
  • (η<sup>4</sup>-1,5-Cyclooctadiene)rhodium chloride dimer
  • 1,5-Cyclooctadiene, rhodium complex
  • 1,5-cyclooctadiene, chloride, (1Z,5Z)-, dirhodium salt
  • Bis((1,5-cyclooctadiene)(chloro)rhodium)
  • Bis((μ-chloro)(η4-1,5-cyclooctadiene)rhodium)
  • Bis((μ-chloro)(η<sup>4</sup>-1,5-cyclooctadiene)rhodium)
  • See more synonyms
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