CAS 137219-86-4

(R)-DM-BINAP

Formula: C₅₂H₄₈P₂

InChI: InChI=1S/C52H48P2/c1-33-21-34(2)26-43(25-33)53(44-27-35(3)22-36(4)28-44)49-19-17-41-13-9-11-15-47(41)51(49)52-48-16-12-10-14-42(48)18-20-50(52)54(45-29-37(5)23-38(6)30-45)46-31-39(7)24-40(8)32-46/h9-32H,1-8H3

InChI key: MXGXXBYVDMVJAO-UHFFFAOYSA-N

SMILES: CC1=CC(=CC(=C1)P(C2=C(C3=CC=CC=C3C=C2)C4=C(C=CC5=CC=CC=C54)P(C6=CC(=CC(=C6)C)C)C7=CC(=CC(=C7)C)C)C8=CC(=CC(=C8)C)C)C

Synonyms:

• (R)-(+)-2,2'-Bis[di(3,5-xylyl)phosphino]-1,1'-binaphthyl
• (R)-(+)-2,2'-Bis[Bis(3,5-dimethylphenyl)phosphino]-1,1'-binaphthyl
• (R)-(+)-2,2'-Bis(di-(3,5-dimethylphenyl)phosphino)-1,1'-binaphthyl, (R)-Xylyl-B
• (R)-XylBINAP

(R)-(+)-XylBINAP

CAS: 137219-86-4

Formula: C₅₂H₄₈P₂

Purity: >97.0%(HPLC)

Color and Shape: White to Almost white powder to crystal

Molecular weight: 734.90

Ref: 3B-X0070

(R)-(+)-2,2'-Bis[di(3,5-xylyl)phosphino]-1,1'-binaphthyl, 98% (R)-(+)-XylBINAP

CAS: 137219-86-4

(R)-(+)-2,2'-Bis[di(3,5-xylyl)phosphino]-1,1'-binaphthyl, 98% (R)-(+)-XylBINAP

Formula: C₅₂H₄₈P₂

Purity: 98%

Color and Shape: white to pale yellow xtl.

Molecular weight: 734.90

Ref: 08-15-0476

(R)-2,2'-Bis(Di-3,5-Xylylphosphino)-1,1'-Binaphthyl

CAS: 137219-86-4

(R)-2,2'-Bis(Di-3,5-Xylylphosphino)-1,1'-Binaphthyl

Formula: C₅₂H₄₈P₂

Purity: 96%,99%ee

Molecular weight: 734.89

Ref: 54-OR1008456

(R)-2,2'-Bis(di-3,5-xylylphosphino)-1,1'-binaphthyl

CAS: 137219-86-4

Formula: C₅₂H₄₈P₂

Purity: 97%

Color and Shape: Solid

Molecular weight: 734.8850

Ref: IN-DA0012YB

(R)-2,2'-Bis(Di-3,5-Xylylphosphino)-1,1'-Binaphthyl

CAS: 137219-86-4

(R)-2,2'-Bis(Di-3,5-Xylylphosphino)-1,1'-Binaphthyl

Formula: C₅₂H₄₈P₂

Purity: 96%,99%ee

Molecular weight: 734.89

Ref: 54-OR1008457

(R)-DM-BINAP

CAS: 137219-86-4

(R)-2,2'-Bis(di-3,5-xylylphosphino)-1,1'-binaphthyl

Formula: C₅₂H₄₈P₂

Purity: 98%

Molecular weight: 734.89

Ref: IN-DG41008

(R)-2,2′-Bis(di-3,5-xylylphosphino)-1,1′-binaphthyl

CAS: 137219-86-4

Purity: 97%

Color and Shape: Solid

Molecular weight: 734.32

Ref: 10-F996365

(R)-(+)-XylBINAP

CAS: 137219-86-4

(R)-(+)-XylBINAP is an asymmetric hydrogenation catalyst that is a diphosphine ligand. It has been used in the kinetic resolution of β-unsaturated aldehydes, where it selectively reduces one enantiomer to give the corresponding alcohols. The chiral nature of these products can be confirmed by NMR spectroscopy and mass spectrometry. In addition, (R)-(+)-XylBINAP has been used in the synthesis of imines and primary amines by reacting with amines or ammonia, respectively. This compound is operational under mild conditions at room temperature and pressure. It is insoluble in water and soluble in common organic solvents such as ether, benzene, chloroform, and acetone. A polarimeter can be used to measure the degree of rotation of polarized light beams passing through a solution containing a substance whose concentration changes when its molarity is changed.

Formula: C₅₂H₄₈P₂

Purity: Min. 95%

Molecular weight: 734.89 g/mol

Ref: 3D-FX60905