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CAS 14243-65-3

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Bromo(triphenylphosphine)gold

Description:
Bromo(triphenylphosphine)gold, with the CAS number 14243-65-3, is a coordination compound featuring gold in a +1 oxidation state, coordinated to triphenylphosphine and a bromide ion. This compound typically appears as a yellow to orange solid and is known for its stability under ambient conditions. It is soluble in organic solvents such as dichloromethane and chloroform, but insoluble in water. The presence of the triphenylphosphine ligand enhances the compound's reactivity and facilitates its use in various organic synthesis reactions, particularly in the formation of gold-containing complexes. Bromo(triphenylphosphine)gold is often utilized in catalysis, especially in reactions involving alkynes and alkenes, and in the preparation of gold nanoparticles. Its unique electronic properties and ability to participate in ligand exchange reactions make it a valuable compound in both academic research and industrial applications. Safety precautions should be taken when handling this compound, as it may pose health risks if ingested or inhaled.
Formula:C18H15AuBrP
InChI:InChI=1S/C18H15P.Au.BrH/c1-4-10-16(11-5-1)19(17-12-6-2-7-13-17)18-14-8-3-9-15-18;;/h1-15H;;1H/q;+1;/p-1
InChI key:InChIKey=UIYUJCNGYSSFGP-UHFFFAOYSA-M
SMILES:[P]([Au+][Br-])(C1=CC=CC=C1)(C2=CC=CC=C2)C3=CC=CC=C3
Synonyms:
  • Gold(1+) Bromide - Triphenylphosphane (1:1:1)
  • Gold, bromo(triphenylphosphine)-
  • Triphenylphosphinegold bromide
  • Bromo(triphenylphosphine)gold
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