CAS 14523-22-9

Rhodium, tetracarbonyldi-μ-chlorodi-

Description:

Rhodium, tetracarbonyldi-μ-chlorodi- is a coordination compound featuring rhodium as the central metal atom, coordinated by carbon monoxide (CO) ligands and chloride ions. This compound is characterized by its unique structure, where two rhodium centers are bridged by two chloride ions, and each rhodium atom is further coordinated to two carbon monoxide ligands. The presence of carbon monoxide contributes to the compound's stability and its ability to participate in various chemical reactions, including catalytic processes. Rhodium complexes are known for their applications in catalysis, particularly in organic synthesis and industrial processes, due to their ability to facilitate reactions such as hydrogenation and carbonylation. The tetracarbonyldi-μ-chlorodi- designation indicates the specific arrangement of ligands around the rhodium centers, which influences the compound's reactivity and properties. Overall, this compound exemplifies the rich chemistry of transition metal complexes, particularly those involving rhodium, which is valued for its catalytic capabilities and unique electronic properties.

Formula: C₄Cl₂O₄Rh₂

InChI: InChI=1S/4CO.2ClH.2Rh/c4*1-2;;;;/h;;;;2*1H;;/q;;;;;;2*+1/p-2

InChI key: InChIKey=FGKDXBICTVUSPK-UHFFFAOYSA-L

SMILES: C(#O)[Rh+]1(C#O)[Cl-][Rh+](C#O)(C#O)[Cl-]1

Synonyms:

• Bis(chlororhodiumdicarbonyl)
• Bis(dicarbonyl(μ-chloro)rhodium)
• Bis(dicarbonylchlororhodium)
• Bis(dicarbonylrhodium chloride)
• Bis(μ-chloro)bis(dicarbonylrhodium)
• Carbon Monoxide
• Chlorodicarbonylrhodium dimer
• Chlorodicarbonylrhodium(I) dimer
• Chlororhodium dicarbonyl dimer
• Di-Mu-Chloro-Bis(Dicarbonylrhodium)
• Di-My-Chloro-Tetracarbonyldirhodium
• Di-mu-chloro-tetracarbonyldirhodium
• Di-Μ-Chloro-Bis(Dicarbonylrhodium)
• Di-Μ-Cloro-Bis(Dicarbonilrodio)
• Di-μ-Chlorotetracarbonyldirhodium(I)
• Di-μ-chlor-bis(dicarbonylrhodium)
• Dicarbonylchlororhodium dimer
• Dicarbonylrhodium chloride dimer
• Dichloride
• Dichlorodirhodiumtetracarbonyl
• Dichlorotetracarbonyldirhodium
• Dirhodium tetracarbonyl dichloride
• Nsc 120116
• Rhodium carbonyl chloride
• Rhodium carbonyl chloride (Rh2(CO)4Cl2)
• Rhodium carbonyl chloride (Rh₂(CO)₄Cl₂)
• Rhodium carbonyl chloride dimer
• Rhodium dicarbonyl chloride dimer
• Rhodium(+1) Cation
• Rhodium, tetracarbonyldi-μ-chlorodi-
• Tetracarbonyl-μ,μ'-dichlorodirhodium
• Tetracarbonyl-μ,μ'-dichlorodirhodium(I)
• Tetracarbonylbis(μ-chloro)dirhodium
• Tetracarbonyldi-μ-chlorodirhodium
• Tetracarbonyldichlorodirhodium
• [Rh(CO)2Cl]2
• tetracarbonyldi-U-chlorodirhodium(I)

Tetracarbonyldi-^m-chlorodirhodium(I), Rh 50.1-52.9%

CAS: 14523-22-9

It is used widely as a chemical for research purposes as well as it acts as a a biochemical for proteomics research. This Thermo Scientific Chemicals brand product was originally part of the Alfa Aesar product portfolio. Some documentation and label information may refer to the legacy brand. The ori

Formula: C₄Cl₂O₄Rh₂

Molecular weight: 388.75

Ref: 02-010547

Chlorodicarbonylrhodium(I) dimer

CAS: 14523-22-9

Chlorodicarbonylrhodium(I) dimer

Formula: RhCl(CO)₂

Color and Shape: red xtl.

Molecular weight: 388.76

Ref: 08-45-0450

Tetracarbonyldi-mu-chlorodirhodium(i)

CAS: 14523-22-9

Formula: C₄Cl₂O₄Rh₂

Purity: 97%

Color and Shape: Solid

Molecular weight: 388.7574

Ref: IN-DA006UWE

Tetracarbonyl dichlorodirhodium(I)

CAS: 14523-22-9

Formula: Rh(CO)₂Cl

Color and Shape: Dark red to red-brown powder

Molecular weight: 388.76

Ref: 7W-GX5542

Rhodium(I) dicarbonyl chloride dimer

CAS: 14523-22-9

Rhodium(I) dicarbonyl chloride dimer

Purity: 98%

Color and Shape: Crystals

Molecular weight: 345.90g/mol

Ref: 54-IN3000

Rhodium Carbonyl Chloride

Controlled Product

CAS: 14523-22-9

Applications Rhodium Carbonyl Chloride is a reagent for rhodium-catalyzed [4+2+1] cycloaddition of in situ generated ene/yne-ene-allenes and carbon monoxide to produce [4+2+1] cycloadducts
References Tian, Z.Y., et al.: Angewandte Chemie Int. Ed.’ 57, 15544 (2018)

Formula: CO·2Cl·2Rh

Color and Shape: Neat

Molecular weight: 388.757

Ref: TR-R318845

Di-¼-chloro-tetracarbonyldirhodium(I)

CAS: 14523-22-9

Di-¼-chloro-tetracarbonyldirhodium(I) is a compound that has been shown to catalyze the carbonylation of various organic substrates in the presence of oxygen. In the presence of a catalytic amount of di-¼-chloro-tetracarbonyldirhodium(I), aniline was converted to 4,4'-dichlorobenzophenone with a yield of 43%. The same reaction also produced 3,3'-dichlorobenzophenone and 2,2'-dichlorobenzophenone as side products. The compound was obtained by reacting hexanes with chlorodirhodium trichloride in the presence of air. The structural analysis was performed using x-ray diffraction technique on an orange powder. It was found that the compound crystallizes in a monoclinic space group with unit cell dimensions a=7.5 Å

Formula: C₄Cl₂O₄Rh₂

Purity: Min. 95%

Molecular weight: 388.76 g/mol

Ref: 3D-PAA52322