CAS 192139-92-7: ((R,R)-2-amino-1,2-diphenylethyl)[(4-tolyl)sulfonyl]amido](p-cymene)ruthenium(ii)chloride

Description: The chemical substance known as ((R,R)-2-amino-1,2-diphenylethyl)[(4-tolyl)sulfonyl]amido](p-cymene)ruthenium(II) chloride, with the CAS number 192139-92-7, is a ruthenium-based complex that features a chiral amine ligand and a sulfonamide moiety. This compound is characterized by its coordination of ruthenium to a p-cymene ligand, which enhances its solubility and reactivity. The presence of the (R,R)-2-amino-1,2-diphenylethyl group contributes to its chirality, making it potentially useful in asymmetric catalysis. The sulfonyl group attached to the amido ligand can influence the electronic properties and sterics of the complex, affecting its reactivity in various chemical transformations. Additionally, the chloride ion serves as a counterion, stabilizing the overall structure. Such ruthenium complexes are often studied for their catalytic properties in organic synthesis, particularly in reactions like hydrogenation and cross-coupling, due to their ability to facilitate bond formation and cleavage under mild conditions.

Formula: C₃₁H₃₅ClN₂O₂RuS

InChI: InChI=1/C21H21N2O2S.C10H14.ClH.Ru/c1-16-12-14-19(15-13-16)26(24,25)23-21(18-10-6-3-7-11-18)20(22)17-8-4-2-5-9-17;1-8(2)10-6-4-9(3)5-7-10;;/h2-15,20-21H,22H2,1H3;4-8H,1-3H3;1H;/q-1;;;+2/p-1/t20-,21-;;;/m1.../s1/rC21H21ClN2O2RuS.C10H14/c1-16-12-14-19(15-13-16)28(25,26)24(27-22)21(18-10-6-3-7-11-18)20(23)17-8-4-2-5-9-17;1-8(2)10-6-4-9(3)5-7-10/h2-15,20-21H,23H2,1H3;4-8H,1-3H3/t20-,21-;/m1./s1

Synonyms:

• [N-[(1R,2R)-2-(Amino-KN)-1,2-diphenylethyl]-4-methylbenzenesulfonamidato-KN]chloro[(1,2,3,4,5,6-η:)-1-methyl-4-(1-methylethyl)benzene]-ruthenium
• RuCl(p-cymene)[(R,R)-Ts-DPEN]
• Chloro{[(1R,2R)-(-)-2-amino-1,2-diphenylethyl](4-toluenesulfonyl)amido}(p-cymene)ruthenium(II)

RuCl[(R,R)-Tsdpen](p-cymene)

CAS: 192139-92-7

• Formula: C₃₁H₃₅ClN₂O₂RuS
• Purity: >90%(HPLC)
• Color and Shape: Orange to Brown powder to crystal
• Molecular weight: 636.21

Ruthenium, [N-[(1R,2R)-2-(amino-κN)-1,2-diphenylethyl]-4-methylbenzenesulfonamidato-κN]chloro[(1,2,3,4,5,6-η)-1-methyl-4-(1-methylethyl)benzene]-

CAS: 192139-92-7

• Formula: C₃₁H₃₅ClN₂O₂RuS
• Purity: 95%
• Color and Shape: Solid
• Molecular weight: 636.2098

RuCl(p-cymene)[(R,R)-Ts-DPEN]

CAS: 192139-92-7

• Purity: 98%
• Molecular weight: 636.21g/mol

RuCl(p-cymene)[(R,R)-Ts-DPEN]

CAS: 192139-92-7

• Purity: 98%
• Color and Shape: Solid
• Molecular weight: 636.21

Chloro{[(1R,2R)-(-)-2-amino-1,2-diphenylethyl](4-toluenesulfonyl)amido}(p-cymene)ruthenium(II), min. 95% RuCl[(R,R)-Tsdpen](p-cymene)

CAS: 192139-92-7

• Formula: C₃₁H₃₅ClN₂O₂RuS
• Purity: min. 95%
• Color and Shape: yellow to dark brown solid
• Molecular weight: 636.21

[((R,R)-2-Amino-1,2-diphenylethyl)[(4-tolyl)sulfonyl]amido](chloro)(η6-p-cymene)ruthenium

CAS: 192139-92-7

Applications [((R,R)-2-Amino-1,2-diphenylethyl)[(4-tolyl)sulfonyl]amido](chloro)(η6-p-cymene)ruthenium is an catalyst used for enantioselective hydrogenation of quinolines, N-Alky Ketimines and antitumor, …

• Formula: C₃₁H₃₅ClN₂O₂RuS
• Color and Shape: Dark Orange
• Molecular weight: 636.21

(R,R)-N-(p-Toluenesulfonyl)-1,2-diphenylethanediamine(chloro)(p-cymene)ruthenium(II)

CAS: 192139-92-7

(R,R)-N-(p-Toluenesulfonyl)-1,2-diphenylethanediamine (chloro)(p-cymene)ruthenium(II) is a reagent that is soluble in organic solvents. It can be used …

• Formula: C₃₁H₃₅ClN₂O₂RuS
• Purity: Min. 95%
• Molecular weight: 636.21 g/mol