CAS 220114-32-9

Ruthenium,[1,1'-(1R)-[1,1'-binaphthalene]-2,2'-diylbis[1,1-bis(3,5-dimethylphenyl)phosphine-kP]][(2R)-1,1-bis(4-methoxyphenyl)-3-methyl-1,2-butanediamine-kN1,kN2]dichloro-, (OC-6-14)-

Description:

The chemical substance known as Ruthenium, with the specified name and CAS number 220114-32-9, is a complex organometallic compound featuring a ruthenium center coordinated with various ligands. This compound is characterized by its chiral binaphthalene backbone, which contributes to its stereochemical properties, making it potentially useful in asymmetric catalysis. The presence of bisphosphine ligands, specifically 1,1-bis(3,5-dimethylphenyl)phosphine, enhances its stability and reactivity, while the inclusion of a diamine ligand, 1,1-bis(4-methoxyphenyl)-3-methyl-1,2-butanediamine, provides additional coordination sites and influences its electronic properties. The dichloro substituents indicate that the compound may participate in various chemical reactions, including substitution and coordination with other substrates. Overall, this ruthenium complex is notable for its potential applications in catalysis, particularly in organic synthesis, due to its unique structural features and the ability to facilitate specific chemical transformations.

Formula: C₇₁H₇₄Cl₂N₂O₂P₂Ru

InChI: InChI=1S/C52H48P2.C19H26N2O2.2ClH.Ru/c1-33-21-34(2)26-43(25-33)53(44-27-35(3)22-36(4)28-44)49-19-17-41-13-9-11-15-47(41)51(49)52-48-16-12-10-14-42(48)18-20-50(52)54(45-29-37(5)23-38(6)30-45)46-31-39(7)24-40(8)32-46;1-13(2)18(20)19(21,14-5-9-16(22-3)10-6-14)15-7-11-17(23-4)12-8-15;;;/h9-32H,1-8H3;5-13,18H,20-21H2,1-4H3;2*1H;/q;;;;+2/p-2/t;18-;;;/m.1.../s1

InChI key: UTQCNMRDWASSEC-OEGAAENXSA-L

SMILES: CC1=CC(=CC(=C1)P(C2=C(C3=CC=CC=C3C=C2)C4=C(C=CC5=CC=CC=C54)P(C6=CC(=CC(=C6)C)C)C7=CC(=CC(=C7)C)C)C8=CC(=CC(=C8)C)C)C.CC(C)[C@H](C(C1=CC=C(C=C1)OC)(C2=CC=C(C=C2)OC)N)N.Cl[Ru]Cl

Synonyms:

• Ruthenium,[(1R)-[1,1'-binaphthalene]-2,2'-diylbis[bis(3,5-dimethylphenyl)phosphine-kP]][(2R)-1,1-bis(4-methoxyphenyl)-3-methyl-1,2-butanediamine-kN,kN']dichloro-, (OC-6-14)- (9CI)

RuCl2[(R)-xylbinap][(R)-daipen]

CAS: 220114-32-9

Formula: C₇₁H₇₄Cl₂N₂O₂P₂Ru

Color and Shape: Yellow to Amber to Dark red powder to crystal

Molecular weight: 1,221.30

Ref: 3B-R0133

Dichloro{(R)-2,2'-bis[di(3,5-xylyl)phosphino]-1,1'-binaphthyl}[(2R)-1,1-bis(4-methoxyphenyl)-3-methyl-1,2-butanediamine]ruthenium(II)

CAS: 220114-32-9

Formula: C₇₁H₇₄Cl₂N₂O₂P₂Ru

Purity: 98%

Color and Shape: Solid

Molecular weight: 1221.2830

Ref: IN-DA003U5K

Dichloro{(R)-2,2'-Bis[Di(3,5-Xylyl)Phosphino]-1,1'-Binaphthyl}[(2R)-1,1-Bis(4-Methoxyphenyl)-3-Methyl-1,2-Butanediamine]Ruthenium(II)

CAS: 220114-32-9

Dichloro{(R)-2,2'-Bis[Di(3,5-Xylyl)Phosphino]-1,1'-Binaphthyl}[(2R)-1,1-Bis(4-Methoxyphenyl)-3-Methyl-1,2-Butanediamine]Ruthenium(II)

Formula: C₇₁H₇₄Cl₂N₂O₂P₂Ru

Purity: ≥95%

Molecular weight: 1221.28

Ref: 54-IN11758

RuCl2[(R)-xylbinap][(R)-daipen]

CAS: 220114-32-9

Purity: 98%

Color and Shape: Solid

Molecular weight: 1221.3

Ref: 10-F987732

Dichloro{(R)-(+)-2,2'-bis[di(3,5-xylyl)phosphino]-1,1'-binaphthyl}[(2R)-(-)-1,1-bis(4-methoxyphenyl)-3-methyl-1,2-butanediamine]ruthenium(II) RuCl₂[(R)-xylbinap][(R)-daipen]

CAS: 220114-32-9

Dichloro{(R)-(+)-2,2'-bis[di(3,5-xylyl)phosphino]-1,1'-binaphthyl}[(2R)-(-)-1,1-bis(4-methoxyphenyl)-3-methyl-1,2-butanediamine]ruthenium(II) RuCl2[(R)-xylbinap][(R)-daipen]

Formula: C₇₁H₇₄Cl₂N₂O₂P₂Ru

Color and Shape: yellow to dark brown or green solid

Molecular weight: 1221.28

Ref: 08-44-0212