CAS 3240-34-4

Iodobenzene diacetate

Description:

Iodobenzene diacetate, with the CAS number 3240-34-4, is an organic compound characterized by the presence of an iodobenzene moiety and two acetate groups. It typically appears as a colorless to pale yellow liquid or solid, depending on its purity and form. This compound is known for its reactivity, particularly in electrophilic aromatic substitution reactions due to the electron-withdrawing nature of the iodine atom. The presence of the acetate groups enhances its solubility in organic solvents and can influence its reactivity in various chemical transformations. Iodobenzene diacetate is often utilized in organic synthesis, particularly in the preparation of more complex molecules and as a reagent in various chemical reactions. Additionally, it may exhibit moderate toxicity, necessitating appropriate safety precautions during handling and use. Overall, its unique structure and functional groups make it a valuable compound in synthetic organic chemistry.

Formula: C₁₀H₁₁IO₄

InChI: InChI=1S/C10H11IO4/c1-8(12)14-11(15-9(2)13)10-6-4-3-5-7-10/h3-7H,1-2H3

InChI key: InChIKey=ZBIKORITPGTTGI-UHFFFAOYSA-N

SMILES: I(OC(C)=O)(OC(C)=O)C1=CC=CC=C1

Synonyms:

• (Diacetoxyiodo)benzene
• Baib
• Benzene, (diacetoxyiodo)-
• Benzene, (dihydroxyiodo)-, diacetate
• Benzene, iodoso-, diacetate
• Bis(Acetyloxy)(Phenyl)-Lambda~3~-Iodane
• Bis(acetato)phenyliodine
• Bis(acetato-O)phenyliod
• Bis(acetato-O)phenyliode
• Bis(acetato-κO)phenyliodine
• Diacetoxy(phenyl)iodine
• Diacetoxyiodo-Benzen
• Iodine, bis(acetato-O)phenyl-
• Iodine, bis(acetato-κO)phenyl-
• Iodobenzene-Acetic Acid (1:2)
• Iodonium, (acetyloxy)phenyl-
• Iodophenyl diacetate
• Iodosobenzene diacetate
• Iodosylbenzene Di(Acetate)
• Iodosylbenzene diacetate
• Nsc 226375
• Nsc 23801
• PIA
• Phenyliodine Diacetate
• Phenyliodine(III) diacetate
• Phenyliodo diacetate
• Phenyliodonium diacetate
• Phenyliodoso acetate
• Phenyliodoso diacetate
• Phenyliodosyl diacetate
• Pida
• [Bis(acetoxy)iodo]benzene
• bis(acetato-O)feniliodo
• bis(acetato-O)phenyliodine
• IODOSOBENZENE I,I-DIACETATE
• IODOBENZENE I,I-DIACETATE
• AURORA KA-6690
• LABOTEST-BB LT00847235
• iodoso-benzendiacetate
• IODOBENZENE DIACETATE
• DIACETOXYIODOSOBENZENE
• (dihydroxyiodo)-benzendiacetate
• bis(acetato-o)phenyl-iodin

Iodobenzene Diacetate

CAS: 3240-34-4

Formula: C₁₀H₁₁IO₄

Purity: >97.0%(T)

Color and Shape: White to Light yellow powder to crystal

Molecular weight: 322.10

Ref: 3B-I0330

Iodosobenzene diacetate, 98+%

CAS: 3240-34-4

Iodosobenzene is used as an oxidizing and acetoxylating agent in organic synthesis. It is actively involved in the preparation of (Z)-3,7-dimethyl-2,6-octadien-1-al(neral) from (Z)-3,7-dimethyl-2,6-octadien-1-ol (nerol) in presence of 2,2,6,6-tetramethylpiperidin-1-oxyl (TEMPO). It is a useful reag

Formula: C₁₀H₁₁IO₄

Purity: 98+%

Color and Shape: White, Crystals or powder or crystalline powder

Molecular weight: 322.10

Ref: 02-B24531

Iodobenzene diacetate

CAS: 3240-34-4

Iodobenzene diacetate

Formula: C₁₀H₁₁IO₄

Purity: 97%

Color and Shape: White to off white Solid-Powder

Molecular weight: 322.09641

Ref: 54-OR7138

Iodobenzene diacetate

CAS: 3240-34-4

Formula: C₁₀H₁₁IO₄

Purity: 97%

Color and Shape: Solid

Molecular weight: 322.0964

Ref: IN-DA0038SY

(Diacetoxyiodo)benzene

CAS: 3240-34-4

(Diacetoxyiodo)benzene

Formula: C₁₀H₁₁IO₄

Purity: 97%

Molecular weight: 322.1

Ref: IN-DG0081

Iodobenzene diacetate

CAS: 3240-34-4

Formula: C₁₀H₁₁IO₄

Purity: ≥ 98.0%

Color and Shape: White to light-yellow crystalline powder

Molecular weight: 322.10

Ref: 7W-GK1787

(Diacetoxyiodo)benzene

CAS: 3240-34-4

Formula: C₁₀H₁₁IO₄

Purity: 98.0%

Color and Shape: Solid, Crystalline Powder

Molecular weight: 322.098

Ref: 10-F091213

Iodobenzene 1,1-diacetate

CAS: 3240-34-4

Iodobenzene 1,1-diacetate (PIDA) is a compound containing a hypervalent iodine. This unusual valence of the iodine makes iodobenzene 1,1-diacetate an ideal oxidizing agent in organic synthesis. Furthermore, it is common practice to use iodobenzene 1,1-diacetate to prepare similar reagents by substituting the acetate groups for the desired functional group (Yusubov, 2019). Due to its low toxicity compared to other iodine derivatives, iodobenzene 1,1-diacetate (PIDA) is a common reagent used in total synthesis in the pharmaceutical and agrochemical industry, to produce sugars, alkaloids, antibiotics, etc (Tohma, 2002).

Formula: C₁₀H₁₁IO₄

Purity: Min. 98 Area-%

Color and Shape: White Powder

Molecular weight: 322.1 g/mol

Ref: 3D-FI10879

(Diacetoxyiodo)benzene

CAS: 3240-34-4

Stability Light and Moisture sensitive
Applications (Diacetoxyiodo)benzene is a hypervalent iodine reagent that is used in conjunction with catalytic amount of sodium azide in acetonitrile, which enables oxidative decarboxylation of 2-aryl carboxylic acid into the corresponding aldehydes, ketones and nitriles.
References Telvekar, V.N., et al.: Synlett., 2778 (2012); Liu, W.B., et al.: Beilstein. J. Org. Chem., 8, 244 (2012);

Formula: C₁₀H₁₁IO₄

Color and Shape: Neat

Molecular weight: 322.1

Ref: TR-D360500