CAS 5344-58-1: (1S,2S,4R,7R)-2-Bromo-4,7-dimethyl-3-oxobicyclo[2.2.1]heptane-7-methanesulfonic acid

Description: (1S,2S,4R,7R)-2-Bromo-4,7-dimethyl-3-oxobicyclo[2.2.1]heptane-7-methanesulfonic acid, with CAS number 5344-58-1, is a bicyclic organic compound characterized by its complex structure, which includes a bromine atom and a methanesulfonic acid functional group. The compound features a bicyclo[2.2.1]heptane framework, which contributes to its unique three-dimensional shape and steric properties. The presence of the 2-bromo substituent introduces reactivity, making it a potential candidate for various chemical transformations. The methanesulfonic acid group enhances its solubility in polar solvents and may impart acidic properties, allowing it to participate in acid-base reactions. Additionally, the specific stereochemistry indicated by the (1S,2S,4R,7R) configuration suggests that the compound may exhibit chiral characteristics, which can influence its biological activity and interactions with other molecules. Overall, this compound's structural features and functional groups make it of interest in synthetic organic chemistry and potentially in medicinal chemistry applications.

Formula: C₁₀H₁₅BrO₄S

InChI: InChI=1S/C10H15BrO4S/c1-9-4-3-6(7(11)8(9)12)10(9,2)5-16(13,14)15/h6-7H,3-5H2,1-2H3,(H,13,14,15)/t6-,7+,9+,10-/m1/s1

InChI key: InChIKey=MFEDKMBNKNOUPA-GOZTYBTRSA-N

SMILES: O=C1C(Br)C2CCC1(C)C2(C)CS(=O)(=O)O

Synonyms:

• (+)-3-Bromo-8-camphorsulfonic acid
• (+)-α-Bromocamphor-π-sulfonic acid
• (1S,2S,4R,7R)-2-Bromo-4,7-dimethyl-3-oxobicyclo[2.2.1]heptane-7-methanesulfonic acid
• (3-Bromo-1,7-Dimethyl-2-Oxobicyclo[2.2.1]Hept-7-Yl)Methanesulfonic Acid
• 8-Bornanesulfonic acid, 3-bromo-2-oxo-, endo-(+)-
• Bicyclo[2.2.1]heptane-7-methanesulfonic acid, 2-bromo-4,7-dimethyl-3-oxo-, (1S,2S,4R,7R)-
• Bicyclo[2.2.1]heptane-7-methanesulfonic acid, 3-bromo-1,7-dimethyl-2-oxo-, (1R,3S,4S,7R)-
• Bicyclo[2.2.1]heptane-7-methanesulfonic acid, 3-bromo-1,7-dimethyl-2-oxo-, [1R-(endo,anti)]-
• Camphor-π-sulfonic acid, α-bromo-, (+)-
• R-(+)-3-Bromocamphor-8-sulfonic acid
• d-α-Bromocamphor-π-sulfonate
• (1R-(endo,Anti))-3-bromo-2-oxobornane-8-sulphonic acid

(+)-3-Bromo-8-camphorsulfonic Acid

CAS: 5344-58-1

Applications A chiral reagent used in optical resolution. References Yamada, S. et al.: Agr. Biol. …

• Formula: C₁₀H₁₅BrO₄S
• Color and Shape: Neat
• Molecular weight: 311.19

4-Hydroxy-D-(-)-2-phenylglycine-13C6 (+)-3-Bromo-8-camphorsulfonic Acid

CAS: 22818-40-2 5344-58-164933-95-5

• Formula: C₂C₆H₉NO₃·C₁₀H₁₅BrO₄S
• Color and Shape: Neat
• Molecular weight: 484.31