CAS 5518-52-5

Tri(2-furyl)phosphine

Description:

Tri(2-furyl)phosphine is an organophosphorus compound characterized by the presence of three 2-furyl groups attached to a central phosphorus atom. This compound typically appears as a colorless to pale yellow liquid or solid, depending on its purity and temperature. It is known for its distinctive aromatic properties due to the furan rings, which contribute to its reactivity and potential applications in organic synthesis and coordination chemistry. Tri(2-furyl)phosphine can act as a ligand in coordination complexes, facilitating the formation of metal-ligand interactions. Its structure allows for various chemical reactions, including oxidation and coordination with transition metals. Additionally, it may exhibit interesting electronic properties due to the conjugated system of the furan rings. Safety considerations should be taken into account when handling this compound, as it may pose health risks if inhaled or ingested. Overall, tri(2-furyl)phosphine is a valuable compound in the field of organophosphorus chemistry, with potential applications in catalysis and materials science.

Formula: C₁₂H₉O₃P

InChI: InChI=1/C12H9O3P/c1-4-10(13-7-1)16(11-5-2-8-14-11)12-6-3-9-15-12/h1-9H

InChI key: DLQYXUGCCKQSRJ-UHFFFAOYSA-N

SMILES: c1cc(oc1)P(c1ccco1)c1ccco1

Synonyms:

• Phosphine, tri-2-furanyl-
• Tri-2-furylphosphine
• Tris-furan-2-yl-phosphine
• Trifuran-2-Ylphosphane

Tri(2-furyl)phosphine

CAS: 5518-52-5

Formula: C₁₂H₉O₃P

Purity: >98.0%(GC)

Color and Shape: White to Yellow to Orange powder to crystal

Molecular weight: 232.17

Ref: 3B-T1643

Tri(2-furyl)phosphine, 97%

CAS: 5518-52-5

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Formula: C₁₂H₉O₃P

Purity: 97%

Color and Shape: White to cream to pale brown or yellow to orange, Crystals or powder or crystalline powder or fused solid

Molecular weight: 232.18

Ref: 02-L13329

Tri-2-furylphosphine, 98+%

CAS: 5518-52-5

Tri-2-furylphosphine, 98+%

Formula: (C₄H₃O)₃P

Purity: 98+%

Color and Shape: white pwdr.

Molecular weight: 232.17

Ref: 08-15-6372

Tri(fur-2-yl)phosphine

CAS: 5518-52-5

Tri(fur-2-yl)phosphine

Formula: C₁₂H₉O₃P

Purity: ≥95%

Color and Shape: Solid-Powder

Molecular weight: 232.17182

Ref: 54-OR10819

Tri(furan-2-yl)phosphine

CAS: 5518-52-5

Formula: C₁₂H₉O₃P

Purity: 98%

Color and Shape: Solid

Molecular weight: 232.1718

Ref: IN-DA003UZH

Tri(2-furyl)phosphine

CAS: 5518-52-5

Tri(2-furyl)phosphine (TFP) is a homogeneous catalyst that catalyzes the palladium-catalyzed coupling of aryl bromides and chlorides to form new chiral organic molecules. The reaction mechanism involves the formation of an activated Pd(0) species, which is converted to a Pd(II) species by the addition of a nucleophile. TFP also has been used in asymmetric synthesis, as it can be used for the synthesis of diastereomeric alcohols, nitriles, amines and amino acids. The use of TFP in cross-coupling reactions has been reported to be both reactive and selective. It has been shown that TFP can be used to synthesize ferrocenecarboxylic acid and chloride derivatives. TFP is also able to cleave prochiral bonds with trifluoroacetic acid or hydrogen bonding interactions with chloride ions.

Formula: C₁₂H₉O₃P

Purity: Min. 97.5%

Color and Shape: Powder

Molecular weight: 232.17 g/mol

Ref: 3D-FT28377

Tri(furan-2-yl)phosphine

CAS: 5518-52-5

Tri(furan-2-yl)phosphine

Formula: C₁₂H₉O₃P

Purity: 98%

Molecular weight: 232.17

Ref: IN-DG154957

Tri(2-furyl)phosphine

Controlled Product

CAS: 5518-52-5

Applications A phopshine ligand used in transition-metal mediated organic synthesis, in particular in wittig reactions to improved (Z) selectivity.
References Andersen N.G. et al.: Chem. Rev., 101, 997 (2001); Appel M. et al.: Eur. J. Org. Chem., 1143, (2002);

Formula: C₁₂H₉O₃P

Color and Shape: Neat

Molecular weight: 232.17

Ref: TR-T793700