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CAS 657408-07-6

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2-Dicyclohexylphosphino-2′,6′-dimethoxybiphenyl

Description:
2-Dicyclohexylphosphino-2′,6′-dimethoxybiphenyl is a phosphine ligand commonly used in organometallic chemistry and catalysis, particularly in transition metal complexes. This compound features a biphenyl backbone with methoxy substituents at the 2 and 6 positions, enhancing its solubility and steric properties. The dicyclohexylphosphino group provides strong donor characteristics, making it effective in stabilizing metal centers in catalytic reactions. The presence of bulky cyclohexyl groups contributes to its steric hindrance, which can influence the selectivity and reactivity of metal complexes. This ligand is often employed in cross-coupling reactions, such as Suzuki or Heck reactions, due to its ability to facilitate the formation of carbon-carbon bonds. Additionally, its unique structural features allow for the tuning of electronic properties, making it a valuable tool in the development of new catalytic systems. Overall, 2-Dicyclohexylphosphino-2′,6′-dimethoxybiphenyl is recognized for its effectiveness in promoting various chemical transformations in synthetic organic chemistry.
Formula:C26H35O2P
InChI:InChI=1S/C26H35O2P/c1-27-23-17-11-18-24(28-2)26(23)22-16-9-10-19-25(22)29(20-12-5-3-6-13-20)21-14-7-4-8-15-21/h9-11,16-21H,3-8,12-15H2,1-2H3
InChI key:InChIKey=VNFWTIYUKDMAOP-UHFFFAOYSA-N
SMILES:P(C1=C(C=CC=C1)C2=C(OC)C=CC=C2OC)(C3CCCCC3)C4CCCCC4
Synonyms:
  • (2,6-Dimethoxy-1,1′-biphenyl-2-yl)dicyclohexylphosphine
  • 2-(Dicyclohexylphosphino)-2′,6′-dimethoxy-1,1′-biphenyl
  • 2-Dicyclohexylphosphino-2',6'-dimethoxy-1,1'-biphenyl
  • 2-Dicyclohexylphosphino-2',6'-dimethoxybipheny
  • 2-Dicyclohexylphosphino-2′,6′-dimethoxybiphenyl
  • Dicyclohexyl(2',6'-Dimethoxybiphenyl-2-Yl)Phosphane
  • Dicyclohexyl(2′,6′-dimethoxy[1,1′-biphenyl]-2-yl)phosphine
  • Dicyclohexyl(2′,6′-dimethoxybiphenyl-2-yl)phosphine
  • Dicyclohexyl({2-[(2,6-Dimethoxyphenyl)Methyl]Phenyl}Methyl)Phosphane
  • Phosphine, dicyclohexyl(2′,6′-dimethoxy[1,1′-biphenyl]-2-yl)-
  • See more synonyms
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